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Citation: QIU Ming-Yan, ZHANG Tian-Yong, YUAN Zhong-Fei. Preparation and Purification Technology of 2-[(4-Hydroxyphenyl) sulfonyl]phenol[J]. Chinese Journal of Applied Chemistry, ;2005, 22(5): 566-568. shu

Preparation and Purification Technology of 2-[(4-Hydroxyphenyl) sulfonyl]phenol

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a Department of Fine Chemical and Engineering, School of ChemicalEngineering and Technology, Tianjin University, Tianjin 300072;
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b Department of Chemical Engineering, Anyang Institute of Technology, Anyang;
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c Nantong Baisheng Chemical Co. Ltd, Nantong

Corresponding author: ZHANG Tian-Yong,
Received Date: 18 July 2004
Available Online: 9 October 2004
Fund Project: 教育部留学回国人员科研启动基金(教外司留[2002]247号) (教外司留[2002]247号)

2-[(4-Hydroxyphenyl) sulfonyl]phenol (2,4'-HPSP),a developer for thermo-sensitive record paper,was prepared from phenol and H₂SO₄ with pseudocumene as solvent.The effects of catalyst type,catalyst amount and reaction time on the yield of 2,4'-HPSP were investigated.Under the optimum conditions,the content of 2,4'-HPSP was 37.52% in the product and the total yield was 95.9%(based on H₂SO₄).The crude product was purified successively with 2% methanol in o-dichlorobenzene and 30% methanol in water.The purity of the final (2,4'-) HPSP was 95.52%,and the total yield was 26.4%.The solvents used in the purification process could be recycled.
- [(hydroxyphenyl) sulfonyl] phenol,
- phenol,
- phosphorous acid,
- pseudocumene
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