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Citation: YIN Han-Dong, WANG Qi-Bao, XUE Sheng-Cai, ZHU Qi. Synthesis,Crystal Structure and Reaction Mechanism of One-dimensional Organotin Complex[(4-F-C₆H₄CH₂)₂Sn(3-O₂CC₅H₄N)₂-(4-F-C₆H₄C₂H₅OH)]_n[J]. Chinese Journal of Applied Chemistry, ;2005, 22(6): 619-623. shu

Synthesis,Crystal Structure and Reaction Mechanism of One-dimensional Organotin Complex[(4-F-C₆H₄CH₂)₂Sn(3-O₂CC₅H₄N)₂-(4-F-C₆H₄C₂H₅OH)]_n

1.
a Department of Chemistry, Liaocheng University, Liaocheng 252059;
2.
b Department of Biology, Liaocheng University, Liaocheng 252059

Corresponding author: YIN Han-Dong,
Received Date: 28 July 2004
Available Online: 30 October 2004
Fund Project: 国家自然科学基金(20271025) (20271025)山东省自然科学基金(L2003B01)资助项目 (L2003B01)

A novel hepta-coordinated organotin complex[(4-F-C₆H₄CH₂)₂Sn(3-O₂CC₅H₄N)₂(4-F-C₆H₄-C ₂H₅OH)]_n was synthesized from the reaction of[(4-F-C₆H₄CH₂)₃Sn]₂O with 3-pyridinecarboxylic acid and characterized by means of elementary analysis,IR and ¹H NMR.The crystal structure was determined by single crystal X-ray diffraction study.The crystal belongs to the monoclinic system with space group P2(1)/c,a=1.763 4(12) nm,b=1.277 6(9) nm,c=1.360 6(9) nm,β=96.991(11)°,Z=4,V=3.043(4) nm 3,D_c=1.575 g/cm³,μ=0.904 mm^-1,F(000)=1 456,R₁=0.040 5,wR₂=0.068 2.In the complex,the tin atom is hepta-coordinated in a distorted pentagonal bipyramid including a bridging pyridyl N atom,by which the one-dimensional infinite chain is formed.The antitumor activity tests for the human tumor cell lines MCF-7 and WiDr show that this complex exhibits a good bioactivity.
- organotin complex,
- pyridinecarboxylic acid,
- synthesis,
- crystal structure,
- bioactivity,
- reaction mechanism
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Synthesis,Crystal Structure and Reaction Mechanism of One-dimensional Organotin Complex[(4-F-C6H4CH2)2Sn(3-O2CC5H4N)2-(4-F-C6H4C2H5OH)]n

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Synthesis,Crystal Structure and Reaction Mechanism of One-dimensional Organotin Complex[(4-F-C₆H₄CH₂)₂Sn(3-O₂CC₅H₄N)₂-(4-F-C₆H₄C₂H₅OH)]_n