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Citation: ZHOU Hong-Ping, HAO Fu-Ying, ZHANG Ju-Zhou, ZHAO Zu-Zhi, LI Dong-Mei, WU Jie-Ying, TIAN Yu-Peng, Hoong-Kun Fun. Synthesis,Characterization and Two-Photon Absorption Properties of a Novel Pyridinium Salt[J]. Chinese Journal of Applied Chemistry, ;2005, 22(6): 610-614. shu

Synthesis,Characterization and Two-Photon Absorption Properties of a Novel Pyridinium Salt

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a School of Chemistry and Chemical Engineering, Anhui University, Hefei 230039;
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b Department of Chemistry, Fuyang Normal College, Fuyang;
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c State Key Laboratory of Coordination Chemistry, Nanjing University, Nanjing;
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d X-ray Crystallography Unit, School of Physics, Universiti Sains Malaysia, 11800 USM, Penang, Malaysia

Corresponding author: TIAN Yu-Peng,
Received Date: 29 August 2004
Available Online: 6 November 2004
Fund Project: 国家自然科学基金(50272001,50335050) (50272001,50335050)安徽省教育厅自然科学基金(2004KJ020,2003KJ218)资助项目 (2004KJ020,2003KJ218)

A novel pyridinium salt with a donor/π-conjugated system/acceptor (D-π-A) structure was synthesized and characterized by IR spectrometry,elemental analysis,thermogravimatric and X-ray diffraction analyses.The single- and two- photon induced fluorescence of the compound were studied.The nonlinear optical properties of the compound were investigated by virtue of 1 064 nm picosecond laser beam,and the results show that the novel pyridinium salt has a TPA coefficient of β=0.104 7 cm/GW,a TPA cross-section of σ=3.247 3×10^-46 cm⁴·s·photon^-1,and the overall conversion efficiency was 1.9% at the pump energy level of 1.677 mJ.The crystallographic data for the structural analysis were deposited with the Cambridge Crystallographic Data Center,CCDC no.242507.
- D-π-A pyridinium salt,
- third-order nonlinear optical property,
- X-ray diffraction,
- Z-scan
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