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Citation: LUO Chun-Hua, YU Mei-Na, ZHAO Ling, CHENG Ge. Synthesis of 2,4,6-Tris (phenyoxy)-1,3,5-triazine Derivatives by Solid-state Reaction[J]. Chinese Journal of Applied Chemistry, ;2005, 22(7): 811-812. shu

Synthesis of 2,4,6-Tris (phenyoxy)-1,3,5-triazine Derivatives by Solid-state Reaction

1.
School of Polymer Science and Engineering, State Key Laboratory of Polymer Materials, Sichuan University, Chengdu 610065

Corresponding author: CHENG Ge,
Received Date: 22 October 2004
Available Online: 27 January 2005
Fund Project: 国家自然科学基金资助项目(50273021) (50273021)

Triaryl cyanurates,2,4,6-tris (phenyoxy)-1,3,5-triazine derivatives,were prepared by solid-state reaction,which was carried out between cyanuric chloride and phenols with the molar ratio of 1:3 in the presence of potassium hydroxide as catalyst at room temperature.It is shown that the yields of the products are mainly affected by the reactivity of phenols due to the substituted group and its position.Under the same conditions,2,4,6-tris (p-methoxyphenyoxy)-1,3,5-triazine was synthesized from p-methoxyphenol in the yield of 89% and 2,4,6-tris (o-chlorophenyoxy)-1,3,5-triazine was synthesized from o-chlorophenol in the yield of 30%.
- solid-state reaction,
- condensation,
- cyanuric chloride,
- tris (phenyoxy) triazine
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