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Citation: YANG Xin-Bin, FU Xiang-Kai, NIU Li-Ming, ZENG Ren-Quan. Preparation and Intercalation of Layered Crystalline Zirconium (Glycine-N,N-dimethylenephosphonate-phosphate)[J]. Chinese Journal of Applied Chemistry, ;2005, 22(7): 784-787. shu

Preparation and Intercalation of Layered Crystalline Zirconium (Glycine-N,N-dimethylenephosphonate-phosphate)

1.
a School of Chemistry and Chemical Engineering, Southwest Normal University, Chongqing 400715;
2.
b Basic Department of Rongchang Campus, Southwest Agricultural University, Chongqing

Corresponding author: FU Xiang-Kai,
Received Date: 22 October 2004
Available Online: 26 January 2005
Fund Project: 重庆市科技攻关项目(20006213)资助 (20006213)

Layered crystalline zirconium (glycine-N,N-dimethylenephosphonate-phosphate)(α-ZGDMPP) was prepared (interlayer distance is 1.52 nm).The intercalation complex of n-butylamine into α-ZGDMPP was also investigated.α-ZGDMPP and its intercalation complex were characterized by elemental analysis,XRD,IR,¹³C CP/MAS NMR and TG methods.The results show that the intercalation behavior of layered α-ZGDMPP is different from that of α-ZP with the formation of host-guest compound.The interlayer distance of α-ZGDMPP is enlarged 1.02 nm,n-butylamine molecules intercalated form bilayers and the carbon chains incline at rough 55°to α-ZGDMPP layers,the intercalated n-butylamine is lost in the temperature range of 150~250℃.
- zirconium glycine-N,N-dimethylenephosphonate-phosphate,
- n-butylamine,
- intercalation
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