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Citation: LI Gui-Hua, WANG Hong-Yi, LI Ming-Xiu. Preparation and Application of Catalyst for Oxidativeesterification of Methacrolein to Methyl Methacrylate[J]. Chinese Journal of Applied Chemistry, ;2005, 22(7): 744-748. shu

Preparation and Application of Catalyst for Oxidativeesterification of Methacrolein to Methyl Methacrylate

1.
a College of Chemistry, Hebei Normal University, Shijiazhuang 050091;
2.
b Chemistry Department, Xingtai University, Xingtai

Corresponding author: LI Ming-Xiu,
Received Date: 28 September 2004
Available Online: 15 January 2005
Fund Project: 河北省科学技术厅(002130103D) (002130103D)河北省自然科学基金(200151)资助项目 (200151)

The two-step reaction for the preparation of methyl methacrylate (MMA) from methacrolein (MAL) via oxidative esterification was simplified to one-stage reaction.The catalysts were prepared by means of impregnation and applied to the oxidative esterification reaction of MAL.The results show that the catalytic activity of catalyst mainly containing Pd is increased by adding one,two or a combination of Pb,Bi and Fe.The yield of MMA can reach to 62.4% in the presence of catalyst Pd₅Bi₂PbFe carried on CaCO₃;the catalyst carried on SiO₂ or ZnO has a good activity;while the catalyst carried on MgCO₃ or ZrO₂ has no activity.When catalyst Pd₅Bi₂PbFe carried on CaCO₃ with loading metal order:Pd,Pb,Bi,Fe was used in the reaction,the yield of MMA was 86.9%.The selectivity to methacrolein was improved observably when rare earth elements were added to catalysts Pd₅Bi₂PbFe.When catalyst Pd₅Bi₂PbFePr/CaCO₃ was used to oxidative-esterification reaction of methacrolein,the yield of MMA could reach to 90.4%.
- catalyst,
- methyl methacrylate,
- methacrolein,
- oxidative esterification reaction
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