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Citation: CHEN Zhen-Feng, ZHANG Ming, SHI Shao-Ming, HUANG Ling, LIANG Hong, XU Qing, YU Kai-Bei. Synthesis,Crystal Structure and Antibacterial Activity of 2-Aminobenzothiazole Silver(Ⅰ) Nitrate[J]. Chinese Journal of Applied Chemistry, ;2005, 22(7): 730-733. shu

Synthesis,Crystal Structure and Antibacterial Activity of 2-Aminobenzothiazole Silver(Ⅰ) Nitrate

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a School of Chemistry and Chemical Engineering, Guangxi Normal University, Guilin 541004;
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b Guilin Medical College, Guilin;
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c Institute of Organic Chemistry of Chengdu, Chinese Academy of Sciences, Chengdu

Corresponding author: CHEN Zhen-Feng,
Received Date: 16 September 2004
Available Online: 17 December 2004
Fund Project: 国家自然科学基金资助项目(20361002) (20361002)

A one-dimensional coordination polymer of Ag(Ⅰ) with 2-aminobenzothiazole,[Ag(C₇H₆N₂S)(NO₃)]_∞(1) was synthesized and characterized by means of elemental analysis,IR spectrum and fluorescence spectrum.Its crystal structure was determined by virture of X-ray single crystal diffraction method.The title compound,C₇H₆AgN₃O₃S,M_r=320.08,crystallized in the monoclinic system with space group P2(1)/c,a=0.683 4(1),b=1.541 6(2),c=0.906 9(1) nm,β=90.05(1)°,Z=4,D_c=(2.225 Mg/m³),V=0.955 4(2) nm³,F(000)=624 and R₁=0.036 2,wR₂=0.070 2(I>2σ(I)).In compound 1,the 2-aminobenzothiazole coordinates to silver (Ⅰ) via its thiazole N atoms,and NO₃^- bridges the adjacent silver (Ⅰ) via its' two O atoms to form a one-dimensional chain structure.The antibacterial activity test result shows that the ligand and complex possess strong inhibition activity to Staphylococcus aureus,escherichia coli,Candida albicans in the concentration range of 5.0×10^-1~6.25×10^-2 g/mL (DMSO as solvent).
- silver(Ⅰ)complex,
- aminobenzothiazole,
- synthesis,
- crystal structure,
- antibacterial activity
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