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Citation: AN Lin, CAI Ya-Hua, YAN Chao-Guo. Syntheses and Extraction Properties of Calix[n]arene Amide Derivatives[J]. Chinese Journal of Applied Chemistry, ;2005, 22(9): 980-983. shu

Syntheses and Extraction Properties of Calix[n]arene Amide Derivatives

AN Lin ^a ,
CAI Ya-Hua ^b ,
YAN Chao-Guo ^b,,

1.
a Department of Medicine, Xuzhou Medical College, Xuzhou;
2.
b College of Chemistry & Chemical Engineering, Yangzhou University, Yangzhou 225002

Corresponding author: YAN Chao-Guo,
Received Date: 14 October 2004
Available Online: 16 April 2005
Fund Project: 江苏省教育厅科研基金项目(04KJB150156) (04KJB150156)

Three N,N-dimethylpropyl tert-butylcalix[n] aryl acetoamides 3a~3c(n=4,6,8) were synthesized in moderate yields by treating ethyl tert-butylcalix[n] aryl acetates with N,N-dimethyl-1,3-diaminopropane,which were prepared by the alkylation of tert-butyicalix[n] arenes with ethyl chloroacetate in a system of K₂CO₃/KI/acetone.The extraction properties of these polydentated amide derivatives with octopus shape for metal cations were tested.Compounds 3a and 3c show especially selective extraction for Na⁺ and K⁺ respectively.
- calixarene,
- amide,
- metal ion,
- extraction,
- suprachemistry
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