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Citation: FENG Li, LIAO Li-Yong, LIU Jiong-Tian, WU Jian-Jun, ZHANG Li, MA Yu-Miao. Assembling of Nano-Sb₂O₃ onto Mica Surface and Its Flame Retardant Properties[J]. Chinese Journal of Applied Chemistry, ;2005, 22(9): 962-966. shu

Assembling of Nano-Sb₂O₃ onto Mica Surface and Its Flame Retardant Properties

1.
School of Chemical Engineering and Technology, China University of Mining and Technology, Xuzhou 221008

Corresponding author: FENG Li,
Received Date: 25 October 2004
Available Online: 20 February 2005
Fund Project: 中国矿业大学科技基金资助项目(OH4508) (OH4508)

The Sb₂O₃ nanoparticles prepared with SbCl₃ via alcoholysis,hydrolysis and processing with the surfactants,were assembled onto mica substrates.The crystal phase,morphology and the assembling behavior of nano-Sb₂O₃ on mica were analyzed by means of XRD,TEM and SEM.The flame retardant properties and mechanisms of nano-Sb₂O₃ and nano-Sb₂O₃/mica complex were studied by combustion test and thermal analysis.The results show that the Sb₂O₃ nanoparticles prepared by this method are cubic crystal,which can be assembled uniformly onto the mica substrate.The nano-Sb₂O₃ particles are characteristic of small size,narrow size distribution,uniform crystal and monodispersed particles can be obtained.Compared with micron-Sb₂O₃,the nano-Sb₂O₃ shows more excellent flame retardant properties.The mass loss of nano-Sb₂O₃/mica complex is 13.5% higher than that of nano-Sb₂O₃.Compared with nano-Sb₂O₃,the plateau range of the mass loss temperature of nano-Sb₂O₃ coordinated with chlorinated paraffin is decreased by about 300℃,the mass loss is increased by about 63.2% and the Absorption peak area increases appreciably.Nano-Sb₂O₃/mica complexes show the same coordinating effect as chlorinated paraffin and possess excellent flame retardant properties.
- Sb₂O₃,
- nanoparticle,
- mica,
- flame retardant,
- chlorinated paraffin
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Assembling of Nano-Sb₂O₃ onto Mica Surface and Its Flame Retardant Properties