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Citation: HE Li-Li, LI Xiang-Gao, WU An-Shu. Synthesis of Aromatic Hydrozone Hole Transport Material and Study of Photographic Performance[J]. Chinese Journal of Applied Chemistry, ;2005, 22(9): 946-949. shu

Synthesis of Aromatic Hydrozone Hole Transport Material and Study of Photographic Performance

1.
Department of Fine Chemicals, School of Chemical Engineering and Technology, Tianjin University, Tianjin 300072

Corresponding author: LI Xiang-Gao,
Received Date: 8 November 2004
Available Online: 10 January 2005
Fund Project: 国家"八六三"计划资助项目(2002AA325050) (2002AA325050)

Synthetic methods of tri-substituted aminobenzaldehyde hydrazones,used as hole transport materials (HTM),were studied.2-Methyl-4-dibenzylaminobenzaldehyde-1,1-diphenydrazone,2-methyl-4-(N-ethyl-N-benzyl)aminobenzaldehyde-1,1-diphenydrazone,4-(N-ethyl-N-benzyl)aminobenzaldehyde-1,1-diphenydrazone and 4-bis(p-methylphenyl)aminobenzaldehyde-1,1-diphenydrazone were prepared by the(reaction) of substituted aromatic aldehydes with 1,1-diphenylhydrazine,and their yields were from 82% to 98%.The compositions and structures of the products were characterized by means of UV,IR,MS and elemental analysis.The HPLC purity is higher than 99.4%.The double-layer organic photoconductors were fabricated with the above four compounds as HTM. The tested results of the photoconductors show that hydrazone a and hydrazone d have excellent photographic performance.
- hydrazone,
- synthesis,
- aromatic aldehyde,
- hole transport material
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