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Citation: DU Feng, CHEN Feng-Qiu, YI Ling-Ming, HUANG Lin-Bing, ZHAN Xiao-Li. Synthesis of(3-(2'-ethoxyethoxy)propyl) lithium[J]. Chinese Journal of Applied Chemistry, ;2005, 22(10): 1149-1151. shu

Synthesis of(3-(2'-ethoxyethoxy)propyl) lithium

1.
Department of Chemical Engineering, Zhejiang University, Hangzhou 310027

Corresponding author: ZHAN Xiao-Li,
Received Date: 17 December 2004
Available Online: 16 April 2005
Fund Project: 国家自然科学基金(20376070)资助项目 (20376070)

1-Chloro-3-(2'-ethoxyethoxy)-propane was prepared from 3-chloro-propanol and ethoxy-ethene with dichloroacetic acid as the catalyst and a yield of 96.2%.3-(2'-Ethoxyethoxy)propyl lithium was(then) synthesised from 1-chloro-3-(2'-ethoxyethoxy)-propane and lithium-sodium alloy in a high yield(86%) in a high vacuum reactor.It can be used as an anion polymerization initiator.
- anionic polymerization initiator,
- (ethoxyethoxy)propyl lithium,
- high vacuum reactor
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