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Citation: ZHAO Jun-Wei, YU Li, WANG Jing-Ping, NIU Jing-Yang. Hydrothermal Synthesis and Crystal Structure of Heteropolycompound[4,4-'bipyH]₂H₄(P₂W₁₈O₆₂)·[4,4-'bipy]_1.5·4H₂O of Dawson-type[J]. Chinese Journal of Applied Chemistry, ;2005, 22(12): 1324-1328. shu

Hydrothermal Synthesis and Crystal Structure of Heteropolycompound[4,4-'bipyH]₂H₄(P₂W₁₈O₆₂)·[4,4-'bipy]_1.5·4H₂O of Dawson-type

1.
Institute of Molecular and Crystal Engineering, School of Chemistry and Chemical Engineering, He'nan University, Kaifeng 475001

Corresponding author: WANG Jing-Ping,
Received Date: 27 January 2005
Available Online: 12 March 2005
Fund Project: 河南省自然科学基金(104110517007) (104110517007)河南省教育厅基金(20011500024)资助项目 (20011500024)

A Dawson-type heteropolycompound[4,4-'bipyH]₂H₄(P₂W₁₈O₆₂)·[4,4-'bipy]_1.5·4H₂O has been synthesized hydrothermally and characterized by means of IR,UV and X-ray single-crystal diffraction methods.X-ray crystal structural analysis indicates that the title compound crystals are triclinic with a space group Pī,and the lattice parameters are as follows:a=1.324 8(3) nm,b=1.411 9(3) nm,c=(2.683 3(5) nm),α=78.51(3) °,β=83.72(3) °,γ=68.07(3) °,V=4.559 4(16) nm³,Z=2,D_c=3.634 g/cm³,R₁=0.055 3,wR₂=0.129 0.The title compound consists of 2 protonated 4,4'-bipy molecules,0.5 discrete 4,4'-bipy molecule,4 H⁺ cations,1 heteropolyanion of[P₂W₁₈O₆₂]^6- and 4 water molecules
- hydrothermal synthesis,
- Dawson structure,
- bipy,
- heteropolycompound
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Hydrothermal Synthesis and Crystal Structure of Heteropolycompound[4,4-'bipyH]2H4(P2W18O62)·[4,4-'bipy]1.5·4H2O of Dawson-type

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通讯作者: 陈斌, bchen63@163.com

Hydrothermal Synthesis and Crystal Structure of Heteropolycompound[4,4-'bipyH]₂H₄(P₂W₁₈O₆₂)·[4,4-'bipy]_1.5·4H₂O of Dawson-type