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Citation: GAO Shu-Yan, ZHANG Xiu-Ying, LEI Xue-Feng, ZHANG Hong-Jie. Salicylaldehyde-5-aminosalicylic Acid Schiff Base and its Rare Earth Complexes: Synthesis,Characterization, and Bacteriostatic Activity[J]. Chinese Journal of Applied Chemistry, ;2006, 23(1): 74-78. shu

Salicylaldehyde-5-aminosalicylic Acid Schiff Base and its Rare Earth Complexes: Synthesis,Characterization, and Bacteriostatic Activity

1.
a College of Chemistry & Environmental Science, Henan Normal University, Xinxiang 453007;
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b Labaratory of Rare Earth Chemistry and Physics, Changchun Institute of Applied Chemistry, Chinese Academy of Sciences, Changchun 130022

Corresponding author: ZHANG Hong-Jie,
Received Date: 1 April 2005
Available Online: 15 September 2005
Fund Project: 国家高技术发展与规划("八六三")项目(2002AA302105,2002AA324080) ("八六三")项目(2002AA302105,2002AA324080)国家自然科学基金委员会批准资助对外交流与合作项目(20340420326) (20340420326)河南省自然科学基金项目(0511022000)资助课题 (0511022000)

Salicylaldehyde-5-aminosalicylic acid Schiff base was obtained from salicylaldehyde and 5-amino-salicylic acid and Nd(Ⅲ), Gd(Ⅲ), and Yb(Ⅲ) complexes with it were synthesized.Elemental analysis, molar conductance, IR,¹H NMR, and TG-DTA measurements of the three rare earth complexes indicate that the Schiff base acts as a quadridentate ligand and the coordination numbers are 7 for Nd³⁺, and 9 for Gd³⁺ and Yb³⁺.The ligand and synthesized rare earth complexes show good bacteriostatic activities against staphyococcus aureus, escherichia cocli and withered grass bacillus.Moreover, the bacteriostatic activities of salicylaldehyde-5-aminosalicylic acid Schiff base and its Nd(Ⅲ), Gd(Ⅲ) and Yb(Ⅲ) complexes are related to the rare-earth elements themselves and increased with the increase of the concentrations of the Schiff base and its complexes.
- salicylaldehyde-aminosalicylic acid Schiff base,
- rare earth complex,
- synthesis,
- bacteriostatic activity
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