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Citation: CAI Lei, LIU Wan-Yi. Oxidation of Cyclohexanone to Adipic Acid Catalyzed by Heteropoly Complex with Dawson Structure[J]. Chinese Journal of Applied Chemistry, ;2006, 23(1): 26-29. shu

Oxidation of Cyclohexanone to Adipic Acid Catalyzed by Heteropoly Complex with Dawson Structure

CAI Lei ,
LIU Wan-Yi ^,

1.
Ningxia Key Laboratory of Energy Source & Engineering, Department of Chemistry and Chemical Engineering, Ningxia University, Yinchuan 750021

Corresponding author: LIU Wan-Yi,
Received Date: 12 March 2005
Available Online: 15 May 2005
Fund Project: 国家自然科学基金资助项目(20441002) (20441002)

A Dawson structure heteropoly complex K₁₀Na₂H₂P₂W₁₆O₆₀·18H₂O was prepared and used to catalyze the synthesis of adipic acid from cyclohexanone, oxidized by 30% hydrogen peroxide without any solvent or phase transfer agent.The results show that the catalyst had a high activity.The influences of reaction conditions such as ligands, amount of catalyst, ratio of reactants, reaction time were studied.Optimal reaction conditions were that n(tungsten):n(sulfosalicylic acid):n(cyclohexanone):n(hydrogen peroxide) was 2:1:100:400, and reflux temperature 98℃, the time 5 h.The isolated yield of adipic acid could reach 76.7%.
- adipic acid,
- cyclohexanone,
- Dawson structure,
- catalytic oxidation
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