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Citation: WU Ying, WEN Di-Jiang, XU Ling, WANG Zhen-Ping, NIU Cai-Hong. Preparation, Photochemical and Electrochemical Properties of (C₁₆H₂₀N₂)₃PMo₁₂O₄₀/PVA Composite Film[J]. Chinese Journal of Applied Chemistry, ;2006, 23(1): 18-21. shu

Preparation, Photochemical and Electrochemical Properties of (C₁₆H₂₀N₂)₃PMo₁₂O₄₀/PVA Composite Film

WU Ying ^a,b ,
WEN Di-Jiang ^b,, ,
XU Ling ^b ,
WANG Zhen-Ping ^a ,
NIU Cai-Hong ^a

1.
a Institute of Chemistry and Chemical Engineering, Suzhou University, Suzhou 215021;
2.
b Institute of Material Engineering, Suzhou University, Suzhou 215021

Corresponding author: WEN Di-Jiang,
Received Date: 16 February 2005
Available Online: 10 June 2005
Fund Project: 国家自然科学基金(20275025) (20275025)江苏省教育厅基金(05KJB150123)资助课题 (05KJB150123)

A novel organic-inorganic complex, (TMB)₃PMA was synthesized.There was an electron transfer between TMB and heteropoly anion, PMA.The UV irradiation could promote the oxidation of TMB, in turn, promotes the electron transfer within the (TMB)₃PMA molecule.After (TMB)₃PMA was doped into PVA to form a thin film, the photochromism of (TMB)₃PMA became stable because the conductive and enclosed action of the hydrogen bonds of PVA.The electrochemical reactions of the (TMB)₃PMA/PVA thin film at the Au electrode were quasi-reversible.(TMB)₃PMA/PVA thin film modified electrode displayed electrocatalytic activity for the reduction of IO₃^-.
- tetramethylbenzidine,
- phosphomolybdic acid,
- polyvinyl alcohol,
- photochemical property,
- electrocatalytic activity
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Preparation, Photochemical and Electrochemical Properties of (C₁₆H₂₀N₂)₃PMo₁₂O₄₀/PVA Composite Film