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Citation: GAO Jian, XU Xing-You, XU Tong-Tao, LIU Qing-Liang. Syntheses,Structures and Toxicities of the New Bicadmium(Ⅱ) Cryptates[J]. Chinese Journal of Applied Chemistry, ;2006, 23(2): 173-178. shu

Syntheses,Structures and Toxicities of the New Bicadmium(Ⅱ) Cryptates

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a Departmemt of Chemistry, University of Science and Technology of China, Hefei 230026;
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b Departmemt of Chemical Engineering, Lianyungang Technical College, Lianyungang;
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c Departmemt of Chemical Engineering, Huaihai Institute of Technology, Lianyungang

Corresponding author: GAO Jian,
Received Date: 23 April 2005
Available Online: 7 August 2005
Fund Project: 江苏省普通高校高新技术产业发展项目(JHB05-51)资助项目 (JHB05-51)

Six bicadmium(Ⅱ) cryptates[Cd₂Lⁿ] were synthesized by the[2+3] Schiff base condensation of 2-aminoethyl-bi(3-aminopropyl) amine with sodium 2,6-diformyl-4-R-phenolate(R=CH₃,CH₃O,(C(CH₃)₃,F,Cl,Br,n=1,2,3,4,5,6,respectively) in the presence of Cd²⁺.After one imine group of[Cd₂L¹] was hydrolyzed and solvent addition,with no ring opening,cryptate[Cd₂L^h] was produced.The structures of the seven complexes were confirmed by elemental analysis,IR,electronic spectrum,and ES-MS.The toxicities of the complexes were evaluated by testing antimicrobial activity against bacterial strains.The complexes were active against four organisms tested with no exception,showing highest antimicrobial activity against staphyloccus aureus.
- aminoethyl-bi(aminopropyl)amine,
- bicadmium(Ⅱ) cryptate,
- spectral characterization,
- toxicity
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