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Citation: SUN Zi-Cai, WUMANJIANG Eli, XU Tong-Yu, ZHANG Ya-Gang. Catalysts for Oxidation of the Ozonolysis Product of Oleic Acid with Oxygen to Make Azelaic Acid[J]. Chinese Journal of Applied Chemistry, ;2006, 23(2): 161-164. shu

Catalysts for Oxidation of the Ozonolysis Product of Oleic Acid with Oxygen to Make Azelaic Acid

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a Xinjiang Technical Institute of Physics and Chemistry, Chinese Academy of Sciences, Urumqi 830011;
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b Graduate School of the Chinese Academy of Sciences, Beijing

Corresponding author: WUMANJIANG Eli,
Received Date: 20 June 2005
Available Online: 30 October 2005
Fund Project: 中国科学院"西部之光"资助项目(2003年度) (2003年度)新疆自治区科技厅攻关项目(05200333003003) (05200333003003)

Oxidation of oleic acid with ozone is an important way to produce azelaic acid.The process contains a two-step reaction,ozonization and further oxidation by oxygen in the presence of a catalyst.A mixed solvent system was used for the first step and a series of new catalysts were respectively introduced into the second step.The activity of each catalyst was studied by determining the concentration of active oxygen(CAO) in the reaction and the selectivity was investigated by comparing the corresponding yield of azelaic acid.The results show that the reactivity order of the catalysts studied is V₂O₅ >MnO₂ >MoO₃ >PbO₂ >Co(OAc)₂·4H₂O >Mn(OAc)₂·4H₂O,and the selectivity order is MoO₃ >PbO₂ >MnO₂ >Co(OAc)₂·4H₂O >Mn(OAc)₂·4H₂O >V₂O₅.With MoO₃ or PbO₂ as the catalyst,the yield of azelaic acid can be maintained above 75%.
- oleic acid,
- ozonization,
- azelaic acid,
- concentration of active oxygen(CAO)
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