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Citation: WANG Qiao-Feng, WANG Hai-Bo, CHEN Hui, QIN Xiang-Yang, SUN Xiao-Li. Study on the Asymmetric Aminohydroxylation of Olefins Catalyzed by a Free Recoverable and Reusable Ligand[J]. Chinese Journal of Applied Chemistry, ;2006, 23(3): 337-339. shu

Study on the Asymmetric Aminohydroxylation of Olefins Catalyzed by a Free Recoverable and Reusable Ligand

1.
Department of Chemistry, School of Pharmacy, Fourth Military Medical University, Xi'an 710032

Corresponding author: SUN Xiao-Li,
Received Date: 26 April 2005
Available Online: 25 August 2005
Fund Project: 国家自然科学基金(20272082)资助项目 (20272082)

Excellent enantioselectives of up to 98% e.e.were achieved in the presence of benzyl N-chlorocarbamate as oxidant and nitrogen source when a free recoverable cinchona ligand was used for homogeneous asymmetric aminohydroxylation(AA) of five olefins.In the AA reaction of styrene,this ligand can be easily recovered and reused for five times without any significant loss in its catalytic efficiency.
- recoverable catalyst,
- free ligand,
- asymmetric aminohydroxylation
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