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Citation: GE Shao-Hui, WU Zhi-Jie, ZHANG Ming-Hui, LI Wei, MU Shi-Cheng, TAO Ke-Yi. Preparation of Supported NiB/MgO Amorphous Alloy by Powder Electroless Plating and its Performance in Catalytic Hydrogenation[J]. Chinese Journal of Applied Chemistry, ;2006, 23(3): 268-272. shu

Preparation of Supported NiB/MgO Amorphous Alloy by Powder Electroless Plating and its Performance in Catalytic Hydrogenation

1.
a Iustitute of New Catalytic Materiasl Science, College of Chemistry, Nankai University, Tianjin 300071;
2.
b Nanotechnology Industrialization Base of China, Tianjin

Corresponding author: ZHANG Ming-Hui,
Received Date: 24 May 2005
Available Online: 24 September 2005
Fund Project: 天津市自然科学基金(重点)资助项目(033802511) (重点)资助项目(033802511)

The supported NiB/MgO amorphous alloy catalyst was prepared by powder electroless plating and applied in the catalytic hydrogenation of sulfolene to sulfolane.The XRD,ICP,HRTEM were used to characterize the as-prepared samples,the Ag loading and amount of KBH₄ in the plating solution were changed to optimize the preparation of NiB/MgO catalyst.The characterizations of XRD and SAED revealed the amorphous structure of the sample,and the results of ICP showed that the load of Ag could improve the Ni loading,resulting in enhancing the catalytic activity.Moreover,the different amounts of KBH₄ in the plating solution could not change the composition of NiB/MgO but has an affect on the load of NiB.
- NiB/MgO,
- amorphous alloy,
- electroless plating,
- hydrogenation
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