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Citation: GUO Meng-Ping, ZHOU Li, HE Ren. Synthesis of P⌒O Coordinated Cyclopalladated Complex and Its Catalytic Activity for Suzuki Cross-Coupling Reaction[J]. Chinese Journal of Applied Chemistry, ;2006, 23(5): 480-483. shu

Synthesis of P⌒O Coordinated Cyclopalladated Complex and Its Catalytic Activity for Suzuki Cross-Coupling Reaction

GUO Meng-Ping ^a,b ,
ZHOU Li ^a ,
HE Ren ^a,,

1.
a State Key Laboratory of Fine Chemicals, Dalian University of Technology, Dalian 116012;
2.
b Department of Chemistry, Yichun Institute, Yichun

Corresponding author: HE Ren,
Received Date: 15 June 2005
Available Online: 12 September 2005
Fund Project: 国家自然科学重点基金(20333060)资助项目 (20333060)

Water-soluble Phosphine Ligand PROPANa was synthesized by an improved method,in which Michael addition and the saponification reaction were completed in one-step with a yield of 87%.Its P⌒O coordinated cyclopalladated complex exhibits a high catalytic activity for Suzuki cross-coupling reaction between 4-bromotoluene and 4-fluorophenylboronic acid in a mixture of aqueous and organic solvents at room temperature.
- PROPANa,
- synthesis,
- Suzuki coupling reaction
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