Citation:
DUAN Hong-Dong, MENG Xia, QIN Da-Wei, LIU Wen-Xia. Rheological Studies on Shear-resistant Properties of Crosslinking Polymer Gel[J]. Chinese Journal of Applied Chemistry,
;2006, 23(7): 743-746.
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The yield stress and shear-resistant properties of crosslinking polymer gel were studied by rheological measurement.It was found that when the concentration of polymer was 2 g/L,the system showed Newton's fluid;when the concentration of polymer was 3 or 4 g/L,the system showed plastic fluid,and the yield stress was 12 or 28 Pa,respectively.The retention value of viscosity of 4 g/L HPAM system was more than those of other systems.When the concentrations of the crosslinking agents were 0.25,0.5,1.0 and 1.5 mmol/L,respectively,the yield stresses were 6.0,20.0,12.0 and 2.0 Pa,respectively.When the pH value of the system was 4.86,the system showed Newton's fluid;when the pH values of the system were 5.60 and 6.46,the system showed Newton's fluid and the yield stresses were 12 and 7 Pa respectively.The strong gels exhibit higher viscosity retention,i.e.higher shear-resistant properties.
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Keywords:
- crosslinking polymer,
- gel,
- yield stress,
- rheological measurements
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