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Citation: WU Dan, XU Mei-Xian, LIN Shen. Synthesis,Crystal Structure and Catalytic Activity of a Waugh Type Polyoxometalate H₁₂[MnMo₉O₃₂(KO)₆][J]. Chinese Journal of Applied Chemistry, ;2006, 23(9): 1000-1005. shu

Synthesis,Crystal Structure and Catalytic Activity of a Waugh Type Polyoxometalate H₁₂[MnMo₉O₃₂(KO)₆]

1.
College of Chemistry and Materials Science, Fujian Normarl University, Fuzhou 350007

Corresponding author: LIN Shen,
Received Date: 20 October 2005
Available Online: 26 March 2006
Fund Project: 福建省自然科学基金资助项目(E0510012) (E0510012)福建省教育厅A类重点项目(JA04167) (JA04167)

A Waugh type polyoxometalate H₁₂[MnMo₉O₃₂(KO)₆] was synthesized and structurally characterized by means of single crystal X-ray diffraction,IR,XRD and TG.The compound crystallized in the trigonal system with space group R3,a=15.538 0(6) nm,b=15.538 0(6) nm,c=12.377 7(5) nm,α=90°,β=90°,γ=120°,V=2 587.98(18) nm³,Z=3,R₁=0.013 4,ωR₂=0.030 8.The catalytic activity of the title compound for the dehydration of cyclohexanol was studied.The conversion of C₆H₁₁OH reached to 69.6 % and the selectivity of C₆H₁₀ was 96% when the amount of catalyst,temperature range and reaction time were 6.6%,170~180℃,30 min,respectively.
- polyoxometalate,
- crystal structure,
- catalytic activity,
- Waugh structure
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Synthesis,Crystal Structure and Catalytic Activity of a Waugh Type Polyoxometalate H₁₂[MnMo₉O₃₂(KO)₆]