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Citation: YIN Yan-Hong, YANG Jin-Xin, YANG Wei-Guang, YUE Hong-Yun, WANG Hui, YANG Shu-Ting. Preparation and Performance of A Polymer Electrolyte Based on Epoxidized Natural Rubber (ENR)/Styrene Butadiene Rubber(SBR)[J]. Chinese Journal of Applied Chemistry, ;2006, 23(11): 1237-1242. shu

Preparation and Performance of A Polymer Electrolyte Based on Epoxidized Natural Rubber (ENR)/Styrene Butadiene Rubber(SBR)

YIN Yan-Hong ^a,b ,
YANG Jin-Xin ^a,b ,
YANG Wei-Guang ^a,b ,
YUE Hong-Yun ^a,b ,
WANG Hui ^a,b ,
YANG Shu-Ting ^a,b,,

1.
a College of Chemistry and Environmental Science, Henan Normal University, Xinxiang 453007;
2.
b Research Institute of New Energy & Material Engineering of Henan Province, Xinxiang 453002

Corresponding author: YANG Shu-Ting,
Received Date: 28 November 2005
Available Online: 20 February 2006
Fund Project: 河南省重大科技攻关(0522020300)资助项目 (0522020300)

Novel polymer films comprising of epoxidized natural rubber(ENR) and styrene butadiene rubber(SBR) were prepared by means of phase-inversion.Thermogravimetric(TG) analysis indicated that the polymer films possessed good thermal stability with a decomposition temperature higher than 300℃.Scanning electron microscopy(SEM) and atomic force microscopy(AFM) techniques were used to evaluate the microstructure.Gel polymer electrolytes(GPEs) were prepared by dipping ENR/SBR based polymer films in 1 mol/L LiClO₄/(propylene carbonate(PC))/(ethylene carbonate(EC)) liquid electrolyte solutions with V(PC):V(EC) being 1:1.Mechanical strength of the GPEs with V(ENR):V(SBR) being 1:1 and ENR at different epoxidized numbers(20%,40% and 60%) reach 184,397,and 243 kg/cm²,respectively.Electrochemical properties were investigated systematically via AC impedance and Liner Sweep Voltammetry(LSV).The results show that GPE prepared with 40%ENR had the highest conductivity of 1.9×10^-3 S/cm and a broad electrochemical stability window of 4.7 V at room temperature.Additionally,excellent interfacial stability between GPE and lithium electrode was obtained.
- epoxidized natural rubber,
- styrene butadiene rubber,
- polymer electrolyte,
- lithium battery,
- AC impedance
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