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Citation: ZHANG Zhi-Li, LI Wei, ZHANG Ming-Hui, TAO Ke-Yi, WANG Quan-Yi, BIAN Jun-Min. Amorphous Alloy Catalysts Applied in Hydrogenation of Dimethyl Aminoureazinic Acid[J]. Chinese Journal of Applied Chemistry, ;2006, 23(12): 1323-1326. shu

Amorphous Alloy Catalysts Applied in Hydrogenation of Dimethyl Aminoureazinic Acid

1.
a Department of Materials Chemistry, College of Chemistry, Nankai University, Tianjin 300071;
2.
b TianJin UCAN Science & Technology Development Co., Ltd., Tianjin

Corresponding author: LI Wei,
Received Date: 16 December 2005
Available Online: 18 March 2006
Fund Project: 国家科技攻关计划项目(2004BA314C) (2004BA314C)天津市自然科学重点基金(033802511)资助项目 (033802511)

A series of supported NiB and NiCoB amorphous alloy catalysts was prepared by means of the metal inducing electroless plating and their catalytic activities were measured by hydrogenation of dimethyl aminoureazinic acid.The results show that the supported amorphous alloy catalysts show a high activity in the hydrogenation reaction.The NiCoB/SiO₂ showed the same catalytic activity as Raney Ni.The best reaction conditions over NiCoB/SiO₂ are as follows: Ni and Co loadings of NiCoB/SiO₂ are 4% and 3% respectively;catalyst is stored after drying;the reaction temperature should be controlled around 60℃.
- hydrogenation of dimethyl aminoureazinic acid,
- NiCoB/SiO₂ catalyst,
- amorphous alloy catalyst
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