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Citation: JI Yi-Gang, ZHOU Yi-Ming, SHAO Yang, TANG Ya-Wen, LU Tian-Hong, SHEN Tao. Synthesis and Electrochemical Behaviors of Al and Co co-Doped α-Ni(OH)₂[J]. Chinese Journal of Applied Chemistry, ;2006, 23(12): 1309-1312. shu

Synthesis and Electrochemical Behaviors of Al and Co co-Doped α-Ni(OH)₂

JI Yi-Gang ^a ,
ZHOU Yi-Ming ^a,, ,
SHAO Yang ^a ,
TANG Ya-Wen ^a ,
LU Tian-Hong ^a,b ,
SHEN Tao ^c

1.
a College of Chemistry and Environment Science, Nan jing Normal University, Nan jing 210097;
2.
b Chang chun Institute of Applied Chemistry, Chinese Academy of Sciences, Changchun;
3.
c Jiang su Highstar Group Company, Nantong

Corresponding author: ZHOU Yi-Ming,
Received Date: 26 December 2005
Available Online: 16 June 2006
Fund Project: 国家自然科学基金(20573057)资助项目 (20573057)南京师范大学预研基金(2005103XYY1809)资助项目 (2005103XYY1809)

Al and Co co-doped α-Ni(OH)₂ sample was prepared by a solid state reaction at a relatively low temperature.Its structure and electrochemical behaviors were investigated.The results of X-ray diffraction(XRD) show that Al and Co co-doped α-Ni(OH)₂ maintains the structure of α-Ni(OH)₂ in 6 mol/L KOH solution for 6 months and keeps the structure of α-Ni(OH)₂ after 30 cycles of charge/discharge.The results of the electrochemical experiments show that Al and Co co-doped α-Ni(OH)₂ exhibits a larger discharge capacity and a higher discharge potential and a high current density property than Al doped α-Ni(OH)₂ and spherical β-Ni(OH)₂.
- solid state reaction,
- Ni(OH)₂,
- electrochemical behaviors,
- co-substituted
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Synthesis and Electrochemical Behaviors of Al and Co co-Doped α-Ni(OH)₂