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Citation: LIN Yong-Sheng, CHEN Xin, TIAN Ling, WU Zhen-Yi, YANG Sen-Gen, FAN Su-Hua, ZHAN Meng-Xiong. Synthesis,Characterization and Photovoltaic Property of Pyrrolidine Ring-fused Metallo-fullerenes[J]. Chinese Journal of Applied Chemistry, ;2007, 24(2): 157-161. shu

Synthesis,Characterization and Photovoltaic Property of Pyrrolidine Ring-fused Metallo-fullerenes

1.
Department of Chemistry, Xiamen University, Xiamen 361005

Corresponding author: YANG Sen-Gen,
Received Date: 8 March 2006
Available Online: 12 June 2006
Fund Project: 福建省自然科学基金(F0210010) (F0210010)

Pyrrolidine ring-fused fullerene derivative(C₆₀Pyr) was prepared by photolysis via the reaction of C₆₀ with CH₃NHCH₂COOMe in 67% yield(based on consumed C₆₀).The product(PyrC₆₀)-Pd(dppe) was obtained by the method of ligand substitution via the reaction of C₆₀Pyr with Pd(dppe)₂ in nitrogen atmosphere at room temperature in 51% yield(relative to C₆₀Pyr).The products were characterized by means of elemental analysis,IR,UV-Vis,X-ray photoelectron spectroscopy and ³¹P NMR.The photovohaic effect(PVE) of the compound on GaAs electrode in electrochemical photovohaic cell were measured.Influences of various redox couples and the thickness of the complex film were observed.The results show that the values of △V and △I for (PyrC₆₀)-Pd(dppe)-GaAs electrode are much greater than those for pure GaAs electrode.So that the photo-electric properities for the compound are excellent,especially in the O₂/H₂O redox couple,the greatest value of photovoltaic potential was 230 mV,and the greatest value of photovoltaic current was 8.7μA.The results showed that (PyrC₆₀)-Pd(dppe)/GaAs electrode at 0.5~1μm for thinckness of(PyrC₆₀)-Pd(dppe) film was the best.
- pyrrolidine,
- fullerene,
- photovohaic effect
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