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Citation: LIU Jian-Guo, LI Ping, LI Ping, ZHENG Jia-Shen. Synthetic Improvement of p-tert-Butoxycarbonyloxystyrene-Intermediate of Monomer of Poly(p-Hydroxystyrene)[J]. Chinese Journal of Applied Chemistry, ;2007, 24(3): 361-364. shu

Synthetic Improvement of p-tert-Butoxycarbonyloxystyrene-Intermediate of Monomer of Poly(p-Hydroxystyrene)

1.
Department of Chemistry, Huazhong University of Science and Technology, Wuhan 430074

Corresponding author: LIU Jian-Guo,
Received Date: 11 May 2006
Available Online: 18 September 2006
Fund Project: 广东省科技攻关资助项目(2006B11801004) (2006B11801004)

p-tert-Butoxycarbonyloxystyrene was synthesized by Wittig reaction with changing solvent medium. The hybrid products were separated and purified by conventional liquid chromatography with neutral Al₂O₃ anhydrous column and n-hexane for elution, which simplifies the separation method. It was shown that the purity of the aim product was higher than 99% and its yield was 60%~70%. The intermediate product p-tert-butoxycarbonyloxybenzaldehyde could be synthesized conveniently and quantitatively. The main byproduct was triphenylphosphine oxide. The aim product, intermediate product and some byproducts were identified with FTIR and NMR.
- photoresist,
- poly(p-hydroxystyrene),
- p-tert-butoxycarbonyloxystyrene
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