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Citation: PAN Zhi-Xin. Study on Stability of Aminoiminomethanesulfonic Acid[J]. Chinese Journal of Applied Chemistry, ;2007, 24(3): 349-352. shu

Study on Stability of Aminoiminomethanesulfonic Acid

PAN Zhi-Xin ^,

1.
College of Chemistry and Material Science, Yantai Normal University, Yantai 264025

Corresponding author: PAN Zhi-Xin,
Received Date: 11 March 2006
Available Online: 28 June 2006

The thermal stability of solid aminoiminomethanesulfonic acid (AIMSO₃H) was studied. The solid aminoiminomethanesulfonic acid and solid aminoiminomethanesulfonic acid hydrate can be decomposed into SO₂ and urea under atmosphere condition. The decomposition increases with temperature. The hydrolysis rate of aminoiminomethanesulfonic acid in water solution was studied. It is influenced by temperature, concentration and pH. The hydrolysis rate equation of aminoiminomethanesulfonic acid is r/(mol·L^-1·s^-1)=k/(L^0.5·mol^-0.5·s^-1)×c(AIMSO₃H)/(mol·L^-)×(c(OH^-)/(mol·L^-1))^0.5. The activation energy of the hydrolysis reaction is 73.56 kJ/mol. Aminoiminomethanesulfonic acid is stable to some oxidants in weak acid condition.
- aminoiminomethanesulfonic acid,
- stability,
- hydrolysis rate equation,
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