Home

Citation: YANG Ze-Ping, LIU Zhong-Fang, HU Xiao-Li, LIU Shao-Pu. Resonance Rayleigh Scattering Spectra of Some Fluoroquinolones Antibiotics-Pd (Ⅱ)-Eosin Y Systems and Their Analytical Application[J]. Chinese Journal of Applied Chemistry, ;2007, 24(3): 261-267. shu

Resonance Rayleigh Scattering Spectra of Some Fluoroquinolones Antibiotics-Pd (Ⅱ)-Eosin Y Systems and Their Analytical Application

1.
School of Chemistry and Chemical Eengineering, Southwest University, Chongqing 400715

Corresponding author: LIU Shao-Pu,
Received Date: 12 March 2006
Available Online: 19 September 2006
Fund Project: 国家自然科学基金资助项目(20475045) (20475045)

In a Briton-Robinson(BR) buffer solution of pH 4.1~5.0, some fluoroquinolone derivatives(norfloxacin, NRF; ciprofloxacin, CPF; ofloxacin, OFL; levofloxacin, LVF) were reacted with palladium(Ⅱ) to form anion chelates, but their resonance Rayleigh scattering(RRS) was very weak. Significant enhancement of RRS intensity and new RRS spectra were observed when these anion chelates further reacted with eosin Y to form ternary complexes. These ternary complexes had similar spectral characteristics and their maximum RRS peaks were located at 368 nm. The optimum condition and the affecting factors were investigated. The linearity ranges and the detection limits for the four fluoroquinolone derivatives were 0~2.4×10^-6 g/mL and 9.4×10^-9 g/mL(CPF), 0~2.4×10^-6 g/mL and 12.8×10^-9 g/mL(NRF), 0~2.2×10^-6 g/mL and 16.2×10^-9 g/mL(LVF), 0~2.8×10^-6 g/mL and 15.6×10^-9 g/mL(OFL), respectively. The composition of the ternary ion association complex was 1:1:1 and its reaction mechanism is discussed. The method has been successfully applied to the determination of NRF in injection and in chicken serum samples and its recovery ranges from 95.0% to 101.5%. As a result, a sensitive and selective RRS method has been developed for the determination of some fluoroquinolones antibiotics.
- resonance rayleigh scattering(RRS),
- fluoroquinolones antibiotics,
- Pd(Ⅱ),
- Eosin Y
1. [1]
  Weihan Zhang , Menglu Wang , Ankang Jia , Wei Deng , Shuxing Bai . Surface Sulfur Species Influence Hydrogenation Performance of Palladium-Sulfur Nanosheets. Acta Physico-Chimica Sinica, 2024, 40(11): 2309043-0. doi: 10.3866/PKU.WHXB202309043
2. [2]
  Renxiao Liang , Zhe Zhong , Zhangling Jin , Lijuan Shi , Yixia Jia . A Palladium/Chiral Phosphoric Acid Relay Catalysis for the One-Pot Three-Step Synthesis of Chiral Tetrahydroquinoline. University Chemistry, 2024, 39(5): 209-217. doi: 10.3866/PKU.DXHX202311024
3. [3]
  Haoyu Sun , Dun Li , Yuanyuan Min , Yingying Wang , Yanyun Ma , Yiqun Zheng , Hongwen Huang . Hierarchical Palladium-Copper-Silver Porous Nanoflowers as Efficient Electrocatalysts for CO₂ Reduction to C₂₊ Products. Acta Physico-Chimica Sinica, 2024, 40(6): 2307007-0. doi: 10.3866/PKU.WHXB202307007
4. [4]
  Guoping Yang , Zhoufu Lin , Xize Zhang , Jiawei Cao , Xuejiao Chen , Yufeng Liu , Xiaoling Lin , Ke Li . Assembly of Y(Ⅲ)-containing antimonotungstates induced by malic acid with catalytic activity for the synthesis of imidazoles. Chinese Chemical Letters, 2024, 35(12): 110274-. doi: 10.1016/j.cclet.2024.110274
5. [5]
  Xiaosheng Zhao , Jie Gao , Kun Shi , Chixiang Zhang , Wenliang Ma , Guo Lyu , Jun Zhang , Jing Lu , Qiangqiang Liu , Xianjin Luo , Kunru Yu , Jianguo Li , Qiang Ge , Jiming Cai , Chang Liu , Zhiyong Qian . A new radioactive microsphere: Y-90 carbon microsphere for selective internal radiation therapy of advanced liver cancer. Chinese Chemical Letters, 2025, 36(8): 110662-. doi: 10.1016/j.cclet.2024.110662
6. [6]
  Wei Peng , Baoying Wen , Huamin Li , Yiru Wang , Jianfeng Li . Exploration and Practice on Raman Scattering Spectroscopy Experimental Teaching. University Chemistry, 2024, 39(8): 230-240. doi: 10.3866/PKU.DXHX202312062
7. [7]
  Ruiqin Feng , Ye Fan , Yun Fang , Yongmei Xia . Strategy for Regulating Surface Protrusion of Gold Nanoflowers and Their Surface-Enhanced Raman Scattering. Acta Physico-Chimica Sinica, 2024, 40(4): 2304020-0. doi: 10.3866/PKU.WHXB202304020
8. [8]
  Yufei Liu , Liang Xiong , Bingyang Gao , Qingyun Shi , Ying Wang , Zhiya Han , Zhenhua Zhang , Zhaowei Ma , Limin Wang , Yong Cheng . MOF-derived Cu based materials as highly active catalysts for improving hydrogen storage performance of Mg-Ni-La-Y alloys. Chinese Chemical Letters, 2024, 35(12): 109932-. doi: 10.1016/j.cclet.2024.109932
9. [9]
  Hongzhi Zhang , Hong Li , Asif Ali Haider , Junpeng Li , Zhi Xie , Hongming Jiang , Conglin Liu , Rui Wang , Jing Zhu . An unexpected role of lanthanide substitution in thermally responsive phosphors NaLnTe2O7: Eu3+ (Ln = Y and Gd). Chinese Journal of Structural Chemistry, 2025, 44(2): 100509-100509. doi: 10.1016/j.cjsc.2024.100509
10. [10]
  Hao Wu , Zhen Liu , Dachang Bai . ¹H NMR Spectrum of Amide Compounds. University Chemistry, 2024, 39(3): 231-238. doi: 10.3866/PKU.DXHX202309020
11. [11]
  Zehua Zhang , Haitao Yu , Yanyu Qi . Design Strategy for Thermally Activated Delayed Fluorescence Materials with Multiple Resonance Effect. Acta Physico-Chimica Sinica, 2025, 41(1): 100006-0. doi: 10.3866/PKU.WHXB202309042
12. [12]
  Shenhao QIU , Qingquan XIAO , Huazhu TANG , Quan XIE . First-principles study on electronic structure, optical and magnetic properties of rare earth elements X (X=Sc, Y, La, Ce, Eu) doped with two-dimensional GaSe. Chinese Journal of Inorganic Chemistry, 2024, 40(11): 2250-2258. doi: 10.11862/CJIC.20240104
13. [13]
  Jinkang Jin , Yidian Sheng , Ping Lu , Zhan Lu . Introducing a Website for Learning Nuclear Magnetic Resonance (NMR) Spectrum Analysis. University Chemistry, 2024, 39(11): 388-396. doi: 10.12461/PKU.DXHX202403054
14. [14]
  Haiyang Jin , Yonghai Hui , Yongfei Zhang , Lijun Gao , Yun Wang . Application and Exploration of Nuclear Magnetic Resonance Spectrometer in Undergraduate Basic Laboratory Teaching. University Chemistry, 2025, 40(3): 245-250. doi: 10.12461/PKU.DXHX202406022
15. [15]
  Haolin Zhan , Qiyuan Fang , Jiawei Liu , Xiaoqi Shi , Xinyu Chen , Yuqing Huang , Zhong Chen . Noise Reduction of Nuclear Magnetic Resonance Spectroscopy Using Lightweight Deep Neural Network. Acta Physico-Chimica Sinica, 2025, 41(2): 2310045-0. doi: 10.3866/PKU.WHXB202310045
16. [16]
  Mei Yan , Qun Wang , Chongshen Guo . Exploring Nobel Prizes: A Journey of Discovery in Physical Chemistry. University Chemistry, 2025, 40(7): 380-386. doi: 10.12461/PKU.DXHX202409063
17. [17]
  Hongyi LI , Aimin WU , Liuyang ZHAO , Xinpeng LIU , Fengqin CHEN , Aikui LI , Hao HUANG . Effect of Y(PO₃)₃ double-coating modification on the electrochemical properties of Li[Ni_0.8Co_0.15Al_0.05]O₂. Chinese Journal of Inorganic Chemistry, 2024, 40(7): 1320-1328. doi: 10.11862/CJIC.20230480
18. [18]
  Hualin Jiang , Wenxi Ye , Huitao Zhen , Xubiao Luo , Vyacheslav Fominski , Long Ye , Pinghua Chen . Novel 3D-on-2D g-C₃N₄/AgI._x._y heterojunction photocatalyst for simultaneous and stoichiometric production of H₂ and H₂O₂ from water splitting under visible light. Chinese Chemical Letters, 2025, 36(2): 109984-. doi: 10.1016/j.cclet.2024.109984
19. [19]
  Bingliang Li , Yuying Han , Dianyang Li , Dandan Liu , Wenbin Shang . One-Step Synthesis of Benorilate Guided by Green Chemistry Principles and in vivo Dynamic Evaluation. University Chemistry, 2024, 39(6): 342-349. doi: 10.3866/PKU.DXHX202311070
20. [20]
  Zhuoming Liang , Ming Chen , Zhiwen Zheng , Kai Chen . Multidimensional Studies on Ketone-Enol Tautomerism of 1,3-Diketones By ¹H NMR. University Chemistry, 2024, 39(7): 361-367. doi: 10.3866/PKU.DXHX202311029

Get Citation

PDF

XML

Metrics

PDF Downloads(1)
Abstract views(331)
HTML views(16)

通讯作者: 陈斌, bchen63@163.com

1.
沈阳化工大学材料科学与工程学院沈阳 110142

Address：Zhongguancun North First Street 2,100190 Beijing, PR China Tel: +86-010-82449177-888

DownLoad: Full-Size Img PowerPoint

Return