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Citation: HE Shu-Hua, HE De-Yong, ZHANG Zhu-Jun. Chemiluminescence System of Ce(Ⅳ)-RhB-Bismerthiazol[J]. Chinese Journal of Applied Chemistry, ;2007, 24(5): 593-595. shu

Chemiluminescence System of Ce(Ⅳ)-RhB-Bismerthiazol

1.
a Department of Chemistry, Yangtze Normal University, Chongqing 408003;
2.
b Department of Chemistry, Jingganshan University, Jingganshan

Corresponding author: HE Shu-Hua,
Received Date: 8 July 2006
Available Online: 20 September 2006
Fund Project: 重庆市教委科学研究项目(KJ051305) (KJ051305)教育部春晖计划资助项目(Z2005-1-55006) (Z2005-1-55006)

A novel chemiluminescence system for the determination of bismerthiazol is described in this paper.It is based on the chemiluminescence reaction of bismerthiazol and Ce(Ⅳ) in nitric acid solution.The emission intensity can be enhanced greatly by Rhodamine B.The chemiluminescence intensity was propor-tional to bismerthiazol concentration over a range of 30~1 000 μg/L.The detection limit was 12 μg/L(3σ) and the relative standard deviation was 2.4% for 500 μg/L bismerthiazol (n=11).The proposed method was successfully applied to the determination of bismerthiazol in water and in rice.The recovery was 96.4%~104.1%.
- bismerthiazol,
- flow injection analysis,
- Rhodamine B,
- chemiluminesce
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