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Citation: ZHOU Jie, YANG Yi-Wen, WU Ping-Dong. Adsorption Properties of Phenylcarbamolyted β-Cyclodextrin for Fluoxetine Enantiomers[J]. Chinese Journal of Applied Chemistry, ;2007, 24(5): 575-579. shu

Adsorption Properties of Phenylcarbamolyted β-Cyclodextrin for Fluoxetine Enantiomers

ZHOU Jie ^a,b,, ,
YANG Yi-Wen ^b ,
WU Ping-Dong ^b

1.
a The School of Pharmacy, Zhengzhou University, Zhengzhou 450001;
2.
b National Laboratory of Secondary Resources Chemical Engineering, Zhejiang University, Hangzhou

Corresponding author: ZHOU Jie,
Received Date: 3 June 2006
Available Online: 15 December 2006

The adsorption selectivity of fluoxetine enantiomers on phenylcarbamolyted β-cyclodextrin was investigated by HPLC on a Cyclobond Ⅰ 2000 DM column.The isothermal adsorption curves were measured at three temperatures.It was found that in a methanol-buffer solution system the adsorptive capacity of Sfluoxetine on phenylcarbamolyted β-cyclodextrin is always greater than that of R-fluoxetine,and the isothermal adsorption of both enantiomers matches the Langumir isotherm adsorption equation and is advantageous adsorption.It was also found that in an acetonitrile-buffer solution system the adsorptive capacity of S-fluoxetine on phenylcarbamolyted β-cyclodextrin is also greater than that of R-fluoxetine,but it matches the Freundlich isotherm equation.Experimental results show that fluoxetine enantiomers can be resolved probably by HPLC on a phenylcarbamolyted β-cyclodextrin column.
- fluoxetine,
- phenylcarbamolyted β-cyclodextrin,
- enantiomer,
- adsorption,
- selectiviy
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