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Citation: WANG Lu-Yao, TIAN Min, HU Wen-Xiang, SHI Zhen. Ferrocenesulfonyl Benzimidazole Derivatives Synthesized under Microwave Irradiation and Their Crystal Structure and Antimicrobial Activity[J]. Chinese Journal of Applied Chemistry, ;2007, 24(5): 507-511. shu

Ferrocenesulfonyl Benzimidazole Derivatives Synthesized under Microwave Irradiation and Their Crystal Structure and Antimicrobial Activity

WANG Lu-Yao ^a ,
TIAN Min ^b ,
HU Wen-Xiang ^a ,
SHI Zhen ^b,,

1.
a Department of Chemistry, Capital Normal University, Beijing;
2.
b Department of Chemistry, Northwest University, Xi'an 710069

Corresponding author: SHI Zhen,
Received Date: 4 January 2007
Available Online: 20 March 2007
Fund Project: 国家自然科学基金(20472067)资助项目 (20472067)北京市科技新星(2006A64)资助项目 (2006A64)

Four Benzimidazole ferrocenesulfonyl derivatives were prepared by the reaction of ferrocenesulfonylchloride with the corresponding benzimidazoles under microwave irradiation.The compounds were characte-rized by means of elemental analysis,MS and ¹H NMR.Henna prismatic crystals of compound 4b were obtained,and the crystal structure was determined by virtue of X-ray diffraction.The crystal is monoclinic with space group P2(1)/c,and the unit cell parameters are a=0.983 45(6) nm,b=1.702 37(11) nm,c=1.180 96(7) nm,α=90°,β=100.998(4)°,γ=90°,V=1.144 3(2) nm³,Z=4,F(000)=1 744,M_r=443.30,D_c=1.517 g/cm³,R₁=0.098 3,wR₂=0.110 1.The preliminary bioassay results indicate that compounds 4a~4d have antimicrobial activity to a certain degree.Compound 4d shows excellent activities against 5 kinds of tested fungus at EC₅₀ 17.12~37.11 mg/L.
- ferrocenesulfonyl benzimidazole,
- synthesis,
- crystal structure,
- antimicrobial activity
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