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Citation: YAN Wen-Hua, KANG Wan-Li, LI Jin-Huan. Synthesis,Crystal Structure and Antibacterial Activity of Di-nbutyltin di-2-(2-formylphenoxy) acetic Ester[J]. Chinese Journal of Applied Chemistry, ;2007, 24(6): 660-664. shu

Synthesis,Crystal Structure and Antibacterial Activity of Di-nbutyltin di-2-(2-formylphenoxy) acetic Ester

1.
MOE Key Lab of Enhanced Oil and Gas Recovery, Daqing Petroleum Institute, Daqing 163318

Corresponding author: KANG Wan-Li,
Received Date: 9 July 2006
Available Online: 20 December 2006
Fund Project: 黑龙江省杰出青年科学基金(J03-11) (J03-11)黑龙江省省教育厅海外学人项目(1055HZ034)资助项目 (1055HZ034)

Di-n-butyltin di-2-(2-formylphenoxy) acetic ester (1) was synthesized by the reaction of di-n-butyl tin oxide with 2-(2-formylphenoxy) acetic acid and azeotropic removal of water with benzene.The compound was characterized by elemental analysis,¹H NMR,FT-IR,and single crystal X-ray diffraction analysis.The crystal belongs to space group C2/c,and the cell parameter are:a=3.324 6(7) nm,b=0.484 54(10) nm,c=2.214 7(5) nm,β=131.373(2)°,V=2.677 3(9) m³,Z=4,F(000)=1 208,D_c=1.467 g/cm⁴,μ=0.999 nm^-1,R₁=0.048 and wR₂=0.104 8.There is one molecule in the unit cell,which adopts a skew-trapezoidal bipyramidal arrangement around the tin atom with hexa-coordination;in addition,there are weak bridging intermolecular SnO-(0.346 8 nm) interactions,and the endocyclic Sn atom is octa-coordinated and exists in distorted hexagonal bipyramidal geometry in a one-dimensional chain.The complex (1) exhibits good antibacterial properties,while the antibacterial activity decreased in the order of compound (1Z) >di-n-butyltin oxide >2-(2-formylphenoxy) acetic acid.
- organotin,
- (formylphenoxy) acetic acid,
- synthesis,
- crystal structure,
- hexagonal bipyramidal geometry,
- one-dimensional chain,
- antibacterial activity
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