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Citation: SUN Li-Ping, NIU Shu-Yun, JIN Jing, ZHANG Li, CHI Yu-Xian, YANG Guang-Di, YE Ling. Synthesis,Structure and Surface Photovoltage of Dinuclear Mn²⁺ Coordination Complex[J]. Chinese Journal of Applied Chemistry, ;2007, 24(8): 905-910. shu

Synthesis,Structure and Surface Photovoltage of Dinuclear Mn²⁺ Coordination Complex

SUN Li-Ping ^a ,
NIU Shu-Yun ^a,, ,
JIN Jing ^a ,
ZHANG Li ^a ,
CHI Yu-Xian ^a ,
YANG Guang-Di ^b ,
YE Ling ^b

1.
a School of Chemistry and Chemical Engineering, Liaoning Normal University, Dalian 116029;
2.
b Key Lab of Supramolecular Structure and Materials of Ministry of Education, Jilin University, Changchun

Corresponding author: NIU Shu-Yun,
Received Date: 23 October 2006
Available Online: 28 December 2006
Fund Project: 国家自然科学基金(20571037和90201018)资助项目 (20571037和90201018)

Two novel dinuclear Mn²⁺ ion coordination complexes Mn₂(C₇H₄O₂Cl)₄(Phen)₂(μ-H₂O)(1) and[Mn₂(btec)(bipy)₂(H₂O)₆]·(H₂O)₂ (2),(phen=1,10-phenanthroline,bipy=2,2'-bipyridyl,H₄btec=1,2,4,5-benzenetetracarboxylic acid) were synthesized by the normal and hydrothermal method.Their structures were determined by single crystal X-ray diffraction.Complex 1 crystallized in the monoclinic system with space group C2/c,a=2.339 3(5),b=1.558 5(3),c=1.559 6(3) nm,β=121.03(3)°,Z=4,R₁=0.075 0,wR₂=0.1602.Complex 2 crystallized in the monoclinic system with space group P2(1)/n,a=1.252 98(8),b=0.769 92(5),c=1.800 90(11) nm,β=100.163 0(10)°,Z=2,R₁=0.029 6,wR₂=0.082 7.In complex 1,two p-chloro-benzoic acid groups together with one water molecule act as the bridges to link the Mn²⁺ ion,forming a dinuclear structure.In complex 2,btec group act as the bridge to coordinate to two Mn²⁺ ions through two p-carboxylic O atoms in a mono-dentate mode,and complex 2 is therefore linked to a dinuclear structure.Complex 2 is further connected to a 2D structure by hydrogen bonds.The surface photovoltage spectra (SPS) of complexes 1 and 2 indicate that they all possess positive surface photovoltage (SPV) responses at 300~800 nm.They exhibit certain semiconductor behavior and take on p-type characteristic.In addition,the differences of their structures have certain effect on their SPV responses.
- dinuclear Mn²⁺ coordination complex,
- hydrogen bond,
- surface photovoltage property,
- surface photovoltage spectrum
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Synthesis,Structure and Surface Photovoltage of Dinuclear Mn2+ Coordination Complex

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Synthesis,Structure and Surface Photovoltage of Dinuclear Mn²⁺ Coordination Complex