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Citation: LI Kun-Lan, GAO Shuang, XI Zu-Wei. Soybean Oil Epoxide via Reaction-Controlled Phase Transfer Catalysis[J]. Chinese Journal of Applied Chemistry, ;2007, 24(10): 1177-1181. shu

Soybean Oil Epoxide via Reaction-Controlled Phase Transfer Catalysis

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a Dalian Polytechnic University, Dalian 116034;
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b Dalian Institute of Chemical Physics, Chinese Academy of Sciences, Dalian

Corresponding author: LI Kun-Lan,
Received Date: 6 November 2006
Available Online: 27 January 2007
Fund Project: 辽宁省教育厅科学技术研究项目(202073424) (202073424)

The epoxidation reaction of soybean oil with 30% hydrogen peroxide and a heteropolyphosphotungstate salt as reaction-controlled phase transfer catalyst, and 1,2-dichloroethane as the solvent under neutral condition was studied. The optimized reaction conditions were 3%(mass fraction) catalyst, molar ratio of H₂O₂ and soybean oil 1.2:1, mass ratio of solvent and soybean oil 3.2:1, reaction temperature 70℃, and reaction time 4 h. Under the above mentioned conditions, the epoxy value was higher than 6%, and the iodine value was less than 0.04 g(I)/g. The catalyst was recycled five times without losing catalyst activity, showing excellent reaction controlled phase transfer catalyst property.
- reaction-controlled phase transfer catalysis,
- soybean oil,
- epoxidation
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