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Citation: YIN Han-Dong, WANG Chuan-Hua, HONG Min. Synthesis, Properties and Crystal Structure of Diorganotin(Ⅳ) Compound with Schiff Base Ligand Pyruvic Acid Isonicotinyl Hydrazone: [Ph₂Sn(C₉H₇N₃O₃)-(H₂O)]₂[J]. Chinese Journal of Applied Chemistry, ;2007, 24(10): 1124-1127. shu

Synthesis, Properties and Crystal Structure of Diorganotin(Ⅳ) Compound with Schiff Base Ligand Pyruvic Acid Isonicotinyl Hydrazone: [Ph₂Sn(C₉H₇N₃O₃)-(H₂O)]₂

1.
Department of Chemistry, Liaocheng University, Liaocheng 252059

Corresponding author: YIN Han-Dong,
Received Date: 28 October 2006
Available Online: 18 January 2007
Fund Project: 国家自然科学基金(20271025) (20271025)山东省自然科学基金(2005ZX09)资助项目 (2005ZX09)

Diorganotin(Ⅳ) compound[Ph₂Sn(C₉H₇N₃O₃)-(H₂O)]₂ was synthesized from the reaction of Ph₂SnO with Schiff base ligand pyruvic acid isonicotinyl hydrazone. The compound was characterized by elemental analysis, IR, and ¹H NMR, and the crystal structure was determined by X-ray single crystal diffraction. The crystal belongs to the orthorhombic system with space group P2₁2₁2₁c, with a=1.142 0(3) nm, b=1.171 3(8) nm, c=3.520(2) nm, V=4.709(5) nm³, Z=4, μ=1.125 mm^-1, D_c=1.501 Mg/m³, F(000)=2 144, R=0.074 5, wR=0.170 4, GOF=1.015. In this molecule, the Sn atom exists in a distorted pentagonal bipyramidal coordination environment in which one water molecule, one tridentate pyruvic acid isonicotinyl hydrazone ligand, and two trans P-cyanobenzyl groups coordinate to each Sn center, and the angle of the axial C10-Sn1-C18 is 166.1(2)°. The antitumor activity tests for the human tumor cell lines MCF-7 and WiDr show that this complex exhibits a good bioactivity.
- organotin(Ⅳ) compound,
- pyruvic acid isonicotinyl hydrazone,
- crystal structure,
- antitumor activity
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Synthesis, Properties and Crystal Structure of Diorganotin(Ⅳ) Compound with Schiff Base Ligand Pyruvic Acid Isonicotinyl Hydrazone: [Ph2Sn(C9H7N3O3)-(H2O)]2

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Synthesis, Properties and Crystal Structure of Diorganotin(Ⅳ) Compound with Schiff Base Ligand Pyruvic Acid Isonicotinyl Hydrazone: [Ph₂Sn(C₉H₇N₃O₃)-(H₂O)]₂