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Citation: LIU Jiang-Hui, XIE Shou-Xin, HU Si, XIE Xiang-Na, XIE Yu-Shan. Determination of Chromium in Cosmetics by ICP-MS[J]. Chinese Journal of Applied Chemistry, ;2007, 24(11): 1340-1342. shu

Determination of Chromium in Cosmetics by ICP-MS

1.
Guangdong Port Inspection & Quarantine Bureau, Guangzhou 510623

Corresponding author: LIU Jiang-Hui,
Received Date: 19 October 2006
Available Online: 15 January 2007

A method was established for the determination of trace Cr in different cosmetic substrates by inductively coupled plasma-mass spectroscopy(ICP-MS). The sample was prepared by microwave digesting in HNO₃-H₂O₂. Comparison research on the dosage of digesting reagent for five different cosmetic substrates was carried out. The working parameters of ICP-MS were optimized, and the matrix effect and the mass interferences were inspected; ⁵²Cr and ⁵³Cr were selected as the target isotopes, ⁷²Ge as the internal standard element, and the influence due to matrix effect were compensated effectively. The experiments showed that the analysis results based on ⁵²Cr and ⁵³Cr was not obvious different, which satisfies the determination of Cr in cosmetics. Standard reference samples were analyzed, with the Cr concentration range of 0.1~100 μg/L. The correlation coefficient was 0.999 9, and with 0.5 mg/kg Cr doped, the average rate of recovery was around 85.3%~104%. The relative standard deviations(RSD) were 1.5%~7.3%, the detection limit of ⁵²Cr 0.052 μg/kg, and the detection limit of ⁵³Cr 0.036 μg/kg.
- Cosmetic,
- Chromium,
- ICP-MS
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