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Citation: HU Xu, LI Hai-Chao, CHEN Li-Yun. Synthesis and Characteristics of C_sH_2s-α,ω-Bis(dehydroabietylhydroxypropyltetramethylethyldiammonium Chloride)[J]. Chinese Journal of Applied Chemistry, ;2007, 24(12): 1439-1442. shu

Synthesis and Characteristics of C_sH_2s-α,ω-Bis(dehydroabietylhydroxypropyltetramethylethyldiammonium Chloride)

HU Xu ^a ,
LI Hai-Chao ^a,b,, ,
CHEN Li-Yun ^a

1.
a Northeast Forestry University, Key Laboratory of Bio-based Material Science and Technology of Ministry of Education, Harbin 150040;
2.
b Qinghai University for Nationalities, Faculty of Chemistry and Life Science, Xining 810007

Corresponding author: LI Hai-Chao,
Received Date: 7 January 2007
Available Online: 16 April 2007

To study the relationship between the "tail" structure and the characteristics of Gemini surfactants,a new gemini surfactant C_sH_2s-α,ω-bis(dehydroabietylhydroxypropyltetramethylethyldiammonium Chloride),here s=2,has been synthesized.Dehydrogenated rosin as hydrophobic "tails" in the structure.The affections of reacttants ratio,reaction temperature and time on the yield of aimed compound have been discussed.The structure of aimed gemini surfactant was confirmed by IR,MS and elemental analysis.Properties of the surfactant were investigated via surface tension.The critical micell concentration(cmc) of the synthesized surfactant was 1.0×10^-4 mol/L and the minimum surface tension was 34.9 mN/m.The results show that the two big "tail" make the synthesized surfactant form micelle more easily.
- synthesis,
- dehydrogenated rosin,
- gemini surfactant
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Synthesis and Characteristics of C_sH_2s-α,ω-Bis(dehydroabietylhydroxypropyltetramethylethyldiammonium Chloride)