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Citation: NIU Hong-Yu, LIU Ying-Hong, SHEN Yue, WANG Jing-Ping. An Organic-inorganic Keggin-type Polyoxometalate with Vanadium Atom as Heteroatom——Synthesis and Crystal Structure of [Co(phen)₃]₄[VW₁₂O₄₀](OH)₅[J]. Chinese Journal of Applied Chemistry, ;2007, 24(12): 1396-1400. shu

An Organic-inorganic Keggin-type Polyoxometalate with Vanadium Atom as Heteroatom——Synthesis and Crystal Structure of [Co(phen)₃]₄[VW₁₂O₄₀](OH)₅

1.
Institute of Molecular and Crystal Engineering, School of Chemistry and Chemical Engineering, Henan University, Kaifeng 475001

Corresponding author: WANG Jing-Ping,
Received Date: 29 December 2006
Available Online: 13 April 2007
Fund Project: 河南省高校新世纪优秀人才支持计划(2005HANCET-02) (2005HANCET-02)

An organic-inorganic complex [Co(phen)₃]₄[VW₁₂O₄₀](OH)₅ was synthesized from NH₄VO₃,NH₂VO₄·2H₂O,CoCl₂ 2H₂O,C₁₂H₈N₁₂ H₂O(phenanthroline) by hydrothermal method and characterized by elemental analysis,IR and X-ray diffraction.The X-ray crystallography indicates that the title compound crystallized in a triclinic lattice,P1 space group,with a=1.638 9(3) nm,b=1.774 4(4) nm,c=18.275(4) nm,α=61.04(3)°,β=78.49(3)°,γ=64.64(3)°,V=4.201 8(15) nm³,Z=1,R₁=0.083 6,wR₂=0.222 8.Structural analysis reveals that the molecule of the title compound is composed of four chiral [Co(phen)3]²⁺ coordination cations,one independent [VW₁₂O₄₀]^3- anion and five dissociative OH-anions.The four coordination cations are located around the anion parallelogram-symmetrically by interaction of electrostatic force and the [VW₁₂O₄₀]^3- anion is located in the center of the parallelogram.The molecules form a 3D network structure through π-π stacking interaction.
- Keggin structure,
- organic-inorganic,
- hydrothermal synthesis,
- crystal structure
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An Organic-inorganic Keggin-type Polyoxometalate with Vanadium Atom as Heteroatom——Synthesis and Crystal Structure of [Co(phen)3]4[VW12O40](OH)5

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通讯作者: 陈斌, bchen63@163.com

An Organic-inorganic Keggin-type Polyoxometalate with Vanadium Atom as Heteroatom——Synthesis and Crystal Structure of [Co(phen)₃]₄[VW₁₂O₄₀](OH)₅