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Citation: LI Ming-Xue, ZHOU Jing, WANG Jing-Ping, WANG Zi-Liang. Synthesis and Crystal Structure of One-dimensional Single-chain Zn(Ⅱ) Complex Containing Pyridine-4-carbaldehyde Thiosemicarbazone and Novel Coordination Mode of Ligand[J]. Chinese Journal of Applied Chemistry, ;2008, 25(1): 48-52. shu

Synthesis and Crystal Structure of One-dimensional Single-chain Zn(Ⅱ) Complex Containing Pyridine-4-carbaldehyde Thiosemicarbazone and Novel Coordination Mode of Ligand

1.
Institute of Molecular and Crystal Engineering, College of Chemistry and Chemical Engineering, Henan University, Kaifeng 475001

Corresponding author: WANG Jing-Ping,
Received Date: 9 February 2007
Available Online: 29 May 2007
Fund Project: 河南省自然科学基金资助项目(0611011900) (0611011900)

The title complex was synthesized from the reaction of pyridine-4-carbaldehyde thiosemicarbazone with zinc acetate and characterized by elemental analysis,IR,UV and X-ray crystal diffraction.The X-ray diffraction revealed that title complex 1 contains one four-coordinated zinc ion connected by two thiosemicarbazone ligands via the pyridyl nitrogen atom of one thiosemicarbazone ligand,the sulfur atom,two oxygen atoms of two acetate anions coordinating through the other thiosemicarbazone ligand,forming a distorted tetrahedron of Zn(Ⅱ) ion.Each ligand adopting the head-to-end coordination mode coordinates to two zinc ion via the pyridine nitrogen and sulphur atoms,respectively.Thus zinc ions are bridge-linked to form an pseudo-helical chain framework.Between the chains,three-dimensional network framework is formed by hydrogen bonding and π-π interactions.It is novel that the pyridine nitrogen atom and sulphur atom of a potential NNS tridentate thiosemicarbazone without using its imine nitrogen adopt the head-to-end NS coordination mode.
- thiosemicarbazone,
- zinc complex,
- crystal structure,
- coordination mode
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