Citation:
MA Zhan-Ying, MU Hong-Mei, SU Bi-Tao, LEI Zi-Qiang. Catalytic Degradation of MB Solution on TiO2/Conjugated Polymer Nanocomposites Under Natural Light[J]. Chinese Journal of Applied Chemistry,
;2008, 25(1): 33-37.
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A new TiO2/polyfurfurylamine(CPFA) nanocomposite was successfully prepared via a process,known as in-situ two-step method(in-situ TSM),from monomer furfurylamine(FA) and TiO2 and used as catalyst to degrade dye MB molecules.The effects of the factors,such as the heat treatment and TiO2 content,on the catalytic property were investigated.Catalytic experiments indicated that under natural light and room temperature conditions,the MB solution was fully decolorized on TiO2/CPFA nanocomposite particles within 2 min.And TiO2/CPFA nanocomposite particles with 42.48% of TiO2,treated at 460℃,exhibited much higher catalytic activity and could keep very high activity on MB decolorization reaction when it was repeatedly used 3 times.TEM results show that in-situ TSM was successful for preparing TiO2-conjugated polymer nanomaterial and the size of TiO2/CPFA particles was about 26 nm and the size distribution was very narrow.XRD results show that TiO2 of the composite material was a mixture of rutile and the content of rutile was about 79%.
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Keywords:
- catalytic property,
- TiO2,
- conjugated polymer,
- nanocomposite,
- natural light
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