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Citation: ZHOU Yu, XU Yu-Fu, HU Xian-Guo. Preparation and Characterization of Molybdenum Disulfide with NH₄⁺ Interlayer[J]. Chinese Journal of Applied Chemistry, ;2008, 25(1): 5-8. shu

Preparation and Characterization of Molybdenum Disulfide with NH₄⁺ Interlayer

ZHOU Yu ^a,b ,
XU Yu-Fu ^a ,
HU Xian-Guo ^a,,

1.
a Institute of Tribology, Hefei University of Technology, Hefei 230009;
2.
b School of Chemical Engineering, Hefei University of Technology, Hefei 230009

Corresponding author: HU Xian-Guo,
Received Date: 9 February 2007
Available Online: 29 April 2007
Fund Project: 国家自然科学基金资助项目(50405071) (50405071)

NH₄⁺/molybdenum disulfide intercalated material was prepared by the exfoliation and restacking process.It could be used to store the single-layered molybdenum disulfide for a long time.It could be also used as a precursor to be inserted with other guest molecules to prepare new intercalated materials.The intercalated material was characterized by XRD and TGA.The results indicated that the interlayer spacing in the MoS₂ was increased from 0.615 nm to 0.954 nm.The content of the inserted NH₄⁺ was determined by elemental analysis and TGA,which showed that the as-prepared NH₄⁺/molybdenum disulfides were(NH₄⁺)_3.1MoS₂ and(NH₄⁺)_2.9MoS₂ respectively.According to the results of XRD and TGA,no change of the intercalation compound was found after it had been saved in air for one month.The degree of intercalation was found to be dependent on the concentration of NH₄Cl,the reaction temperature and time.The NH₄⁺/molybdenum disulfide with the biggest interlayer spacing was obtained when the concentration of NH₄Cl was 1.0%,reaction tempe-rature 30℃ and the reaction time 12 h.
- molybdenum disulfide,
- NH₄⁺,
- intercalation compound
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Preparation and Characterization of Molybdenum Disulfide with NH₄⁺ Interlayer