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Citation: LI Yan-Fei, XIE Chuan. Synthesis of 4-[p-Benzoyl(thiophenyl) phenyl]Phenyl Iodonium Hexafluorophosphate[J]. Chinese Journal of Applied Chemistry, ;2008, 25(2): 251-253. shu

Synthesis of 4-[p-Benzoyl(thiophenyl) phenyl]Phenyl Iodonium Hexafluorophosphate

LI Yan-Fei ,
XIE Chuan ^,

1.
College of Chemical Engineering, Sichuan University, Chengdu 610065

Corresponding author: XIE Chuan,
Received Date: 11 February 2007
Available Online: 16 June 2007

4-[p-Benzoyl(thiophenyl) phenyl] phenyl iodonium hexafluorophosphate(Ⅲ) was synthesized from iodobenzene and diphenyl sulfide as main starting materials through Friedel-Crafts acylation,substitution reaction and metathesis.Its structure was identified by UV,¹H NMR,IR and MS.The optimal reaction conditions were dertermined through orthogonal experiment to be:2.033 g of 4-thiophenyl benzophenone,3.294 g of hydroxyl(tosyloxy)iodobenzene,the mol ratio of catalysts(acetic anhydride/concentrated sulfuric acid) 1.5,reaction temperature of 60℃ and time of 24 h.The yield was 47.9%.The photoinitiability of the product was tested.
- iodonium salt,
- photoinitiator,
- synthesis,
- orthogonal experiment,
- photoinitiability
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