Home

Citation: WANG Guang-Hui, WU Yan-Lin, DENG Nan-Sheng. β-Cyclodextrin Enhanced Photodegradation of 2,2-Bis(4-hydroxy-3-methylphenyl)propane by UV Irradiation[J]. Chinese Journal of Applied Chemistry, ;2008, 25(2): 177-180. shu

β-Cyclodextrin Enhanced Photodegradation of 2,2-Bis(4-hydroxy-3-methylphenyl)propane by UV Irradiation

1.
a Department of Environmental Engineering, East China Institute of Technology, Fuzhou 344000;
2.
b Environmental Protection Administration, Qingpu District, Shanghai;
3.
c School of Resources and Environmental Science, Wuhan University, Wuhan

Corresponding author: WANG Guang-Hui,
Received Date: 11 February 2007
Available Online: 30 June 2007
Fund Project: 国家自然基金(20477031) (20477031)江西省自然基金(2007GZH04477) (2007GZH04477)江西省教育厅(2006[212])资助项目 (2006[212])

Inclusion complex of 2,2-bis(4-hydroxy-3-methylphenyl)propane(BPC) with β-cyclodextrin(β-CD) was studied by using steady-state fluorescence spectroscopy.A 1:1 inclusion complex can be concluded with the formation constant of 4.94×10³ L/mol.The photodegradation behavior of BPC in aqueous solutions with β-CD was investigated under UV irradiation(λ_max=254 nm).The results show that β-CD can enhance the photodegradation of bisphenol C in aqueous solution.The photodegradation of BPC in aqueous solution was found to follow pseudo-first order kinetics law.After 60 min of UV irradiation,β-CD could increase the photodegradation efficiency from 36% to 86% for 10 mg/L BPC.There was no obvious variation for the photodegradation rate of BPC in a pH range from 2 to 8.However,there was obvious increase above pH 8.The photodegradation rate of BPC increased with increasing concentration of β-CD,and there was no further increase in the photodegradation rate when concentration of β-CD exceeded 8.0×10^-5 mol/L.The enhancement of photodegradation of BPC is mainly resulted from the lower bonding energy between some atoms in the BPC molecule after inclusion interaction with β-CD.
- Bisphenol C,
- β-cyclodextrin,
- photodegradation,
- enhancement
1. [1]
  Chao Liu , Huan Yu , Jiaming Li , Xi Yu , Zhuangzhi Yu , Yuxi Song , Feng Zhang , Qinfang Zhang , Zhigang Zou . 具有光热效应的多级Ti₃C₂/Bi₁₂O₁₇Br₂肖特基异质结简单合成及其太阳能驱动抗生素光降解的研究. Acta Physico-Chimica Sinica, 2025, 41(7): 100075-0. doi: 10.1016/j.actphy.2025.100075
2. [2]
  Bing LIU , Huang ZHANG , Hongliang HAN , Changwen HU , Yinglei ZHANG . Visible light degradation of methylene blue from water by triangle Au@TiO₂ mesoporous catalyst. Chinese Journal of Inorganic Chemistry, 2024, 40(5): 941-952. doi: 10.11862/CJIC.20230398
3. [3]
  Jiahui YU , Jixian DONG , Yutong ZHAO , Fuping ZHAO , Bo GE , Xipeng PU , Dafeng ZHANG . The morphology control and full-spectrum photodegradation tetracycline performance of microwave-hydrothermal synthesized BiVO₄:Yb³⁺,Er³⁺ photocatalyst. Journal of Fuel Chemistry and Technology, 2025, 53(3): 348-359. doi: 10.1016/S1872-5813(24)60514-1
4. [4]
  Yichang Liu , Li An , Dan Qu , Zaicheng Sun . “双碳”背景下的综合设计实验——以PbCrO₄催化甲基蓝的光降解速率常数测定为例. University Chemistry, 2025, 40(6): 222-229. doi: 10.12461/PKU.DXHX202407105
5. [5]
  Changjun You , Chunchun Wang , Mingjie Cai , Yanping Liu , Baikang Zhu , Shijie Li . Improved Photo-Carrier Transfer by an Internal Electric Field in BiOBr/N-rich C₃N₅ 3D/2D S-Scheme Heterojunction for Efficiently Photocatalytic Micropollutant Removal. Acta Physico-Chimica Sinica, 2024, 40(11): 2407014-0. doi: 10.3866/PKU.WHXB202407014
6. [6]
  Jianmin Hao , Ruifeng Wu , Ying Wang , Yijia Bai , Xuechuan Gao , Yuying Du . Reform and Practice of Physical Chemistry Course Based on Enhanced Process Assessment and Evaluation. University Chemistry, 2024, 39(8): 78-83. doi: 10.3866/PKU.DXHX202311103
7. [7]
  Biao Zuo , Yizhi Zhang , Zhengkai Chen , Houkuan Tian , Yongneng Wang , Wei Zhang , Weizu Wang , Xuming Zheng , Xinping Wang . Strengthening the Functions of Academic Research and Promoting the Integration of Science and Education: Exploration Ways to Cultivate the Talents of Undergraduate Chemistry Students. University Chemistry, 2024, 39(11): 38-43. doi: 10.3866/PKU.DXHX202402066
8. [8]
  Lei Wang , Panpan Zhang , Zhiyuan Guo , Jing Wang , Jie Ma , Zhi-yong Ji . Electrochemical lithium extraction by the faradaic materials: advances, challenges and enhancement approaches. Acta Physico-Chimica Sinica, 2026, 42(1): 100127-0. doi: 10.1016/j.actphy.2025.100127
9. [9]
  Menglan Wei , Xiaoxia Ou , Yimeng Wang , Mengyuan Zhang , Fei Teng , Kaixuan Wang . S-scheme heterojunction g-C₃N₄/Bi₂WO₆ highly efficient degradation of levofloxacin: performance, mechanism and degradation pathway. Acta Physico-Chimica Sinica, 2025, 41(9): 100105-0. doi: 10.1016/j.actphy.2025.100105
10. [10]
  Zhangshu Wang , Xin Zhang , Jixin Han , Xuebing Fang , Xiufeng Zhao , Zeyu Gu , Jinjun Deng . Exploration and Design of Experimental Teaching on Ultrasonic-Enhanced Synergistic Treatment of Ternary Composite Flooding Produced Water. University Chemistry, 2024, 39(5): 116-124. doi: 10.3866/PKU.DXHX202310056
11. [11]
  Bei Liu , Heng Li , Mei Yang , Yijiang Liu . Teaching Reform and Exploration in Polymer Chemistry with an “Experiment-Intensified” Approach for Masters in Materials and Chemical Engineering. University Chemistry, 2025, 40(4): 10-14. doi: 10.3866/PKU.DXHX202401010
12. [12]
  Chengxin Chen , Hongfei Shi , Xiaoyan Cai , Liang Mao , Zhe Chen . Enhanced bifunctional photocatalytic performances for H₂ evolution and HCHO elimination with an S-scheme CoWO₄/CdIn₂S₄ heterojunction. Acta Physico-Chimica Sinica, 2025, 41(12): 100155-0. doi: 10.1016/j.actphy.2025.100155
13. [13]
  Zhiqiang XING , Jinling LIU , Mingmin SU , Lei ZHANG , Lijun YANG . CoNi dual-single-atom catalyst for electrocatalytic H₂O₂ production and in situ electro-Fenton degradation of pollutants. Chinese Journal of Inorganic Chemistry, 2025, 41(12): 2479-2490. doi: 10.11862/CJIC.20250181
14. [14]
  Guangming YIN , Huaiyao WANG , Jianhua ZHENG , Xinyue DONG , Jian LI , Yi'nan SUN , Yiming GAO , Bingbing WANG . Preparation and photocatalytic degradation performance of Ag/protonated g-C₃N₄ nanorod materials. Chinese Journal of Inorganic Chemistry, 2024, 40(8): 1491-1500. doi: 10.11862/CJIC.20240086
15. [15]
  Tengyue ZHANG , Jingjing FENG , Zili LIANG , Jia′nan DAI , Jing MA . Optimization of C-doped BiVO₄ performance for tetracycline degradation using response surface methodology-assisted orthogonal experiments. Chinese Journal of Inorganic Chemistry, 2025, 41(12): 2561-2574. doi: 10.11862/CJIC.20250104
16. [16]
  Yingqi BAI , Hua ZHAO , Huipeng LI , Xinran REN , Jun LI . Perovskite LaCoO₃/g-C₃N₄ heterojunction: Construction and photocatalytic degradation properties. Chinese Journal of Inorganic Chemistry, 2025, 41(3): 480-490. doi: 10.11862/CJIC.20240259
17. [17]
  Yadan Luo , Hao Zheng , Xin Li , Fengmin Li , Hua Tang , Xilin She . Modulating reactive oxygen species in O, S co-doped C₃N₄ to enhance photocatalytic degradation of microplastics. Acta Physico-Chimica Sinica, 2025, 41(6): 100052-0. doi: 10.1016/j.actphy.2025.100052
18. [18]
  Rui LIU , Xinjun ZHOU , Tao WANG . Photocatalytic degradation performance of tetracycline by MOF-74-Mn/g-C₃N₄ Z-type heterojunction. Chinese Journal of Inorganic Chemistry, 2025, 41(9): 1796-1804. doi: 10.11862/CJIC.20250033
19. [19]
  Min WANG , Dehua XIN , Wei ZHANG , Haiying YANG , Yuchun WANG , Zhaorong LIU , Meng SHI , Le SHI . Preparation and full-spectrum catalytic degradation performance of nitrogen vacancy g-C₃N₄/Bi/BiOBr/BiOI heterojunction material. Chinese Journal of Inorganic Chemistry, 2025, 41(11): 2283-2298. doi: 10.11862/CJIC.20250109
20. [20]
  Kexin Dong , Chuqi Shen , Ruyu Yan , Yanping Liu , Chunqiang Zhuang , Shijie Li . Integration of Plasmonic Effect and S-Scheme Heterojunction into Ag/Ag₃PO₄/C₃N₅ Photocatalyst for Boosted Photocatalytic Levofloxacin Degradation. Acta Physico-Chimica Sinica, 2024, 40(10): 2310013-0. doi: 10.3866/PKU.WHXB202310013

Get Citation

PDF

XML

Metrics

PDF Downloads(1)
Abstract views(450)
HTML views(33)

通讯作者: 陈斌, bchen63@163.com

1.
沈阳化工大学材料科学与工程学院沈阳 110142

Address：Zhongguancun North First Street 2,100190 Beijing, PR China Tel: +86-010-82449177-888

DownLoad: Full-Size Img PowerPoint

Return