Citation:
YANG Chun-Hai, ZHANG Sheng-Hui, YU Ai-Nong, HU Chen-Guo, HU Sheng-Shui. Electrochemical Behavior of Hymecromone and Its Voltammetric Determination at Congo Red-functionalized Water-soluble Multi-walled Carbon Nanotube Film Electrode[J]. Chinese Journal of Applied Chemistry,
;2008, 25(4): 449-454.
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Fabrication of water-soluble multi-wall carbon nanotubes (MWNTs-CR) film modified glassy carbon electrode (MWNTs-CR/GCE) was carried out via the non-covalent modification of congo red for MWNTs.The electrochemical behavior of hymecromone at MWNTs-CR/GCE was investigated by linear sweep voltammetry (LSV),successive cyclic voltammetry and chronocoulometry.Compared with that at bare GCE,the electrochemical response of hymecromone at MWNTs-CR/GCE was greatly enhanced,which was further amplified by the addition of trace cetyltrimethylammonium bromide (CTAB) in solution.In a range of 8.0×10-8~4.0×10-6 mol/L,the oxidation peak current was linear with hymecromone concentration and a low detection limit of 2.0×10-8 mol/L was obtained for 300 s accumulation at open circuit.This method was applied to determine the content of hymecromone in the compound hymecromone tablet sample,the results were satisfactory.
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