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Citation: SHI Wen-Bing. Flow-injection Chemiluminescence Analysis of Propantheline Bromide in Microemulsion[J]. Chinese Journal of Applied Chemistry, ;2008, 25(5): 583-586. shu

Flow-injection Chemiluminescence Analysis of Propantheline Bromide in Microemulsion

SHI Wen-Bing ^,

1.
Department of Chemisty, Yangtze Teacher's College, Fuling Chongqing 408003

Corresponding author: SHI Wen-Bing,
Received Date: 6 May 2007
Available Online: 3 August 2007
Fund Project: 重庆市教委资助项目(KJ061306) (KJ061306)

Under acidic condition,the nitrogen atom in propantheline bromide was easily protonated and formed ion-complex with negative ion AuCl₄^-.The ion-complex was extacted with dichloromethane.When the ion-complex entered a reversed micellar microemulsion of cetyltrimethylammonium chlorine containing luminol,the dissociated AuCl₄^- reacted with luminol,producing an analytical chemiluminescnece signal.Under the optimum conditions,the linear range is from 0.001 to 10×10^-6 g/mL and the limit of detection is 0.04×10^-9 g/mL with a relative standard deviation (n=11) of ca.1.32% for 1.0×10^-6 g/mL propantheline bromide.The method has been applied to the determination of the studied drug in tablets and biological fluids successfully.
- microemulsion,
- propantheline bromide,
- chemiluminescence
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