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Citation: REN Jun, Wang Shi-Min, WU Li-Fang, FANG Zhang-Jian, WU Jie, XU Zu-Xun. Synthesis and Properties of Novel NLO Molecules with Structure of Thiazole and Schiff Base[J]. Chinese Journal of Applied Chemistry, ;2008, 25(5): 505-509. shu

Synthesis and Properties of Novel NLO Molecules with Structure of Thiazole and Schiff Base

1.
Ministry of Education Key Laboratory for the Synthesis and Application of Organic Functional Molecules, Hubei University, Wuhan 430062

Corresponding author: Wang Shi-Min,
Received Date: 9 April 2007
Available Online: 10 November 2007
Fund Project: 国家自然科学基金(20472017)资助项目 (20472017)

Four new second-order nonlinear optical (NLO) molecules derivated from thiazole and containing the structure of Schiff base were synthesized.These target molecules were confirmed by IR,UV,NMR and elemental analysis,and 2nd-order polarizability of those molecules were determined by a solvatochromic method.The structure of a five-membered heterocyclic ring and Schiff base improved the thermally stability and transparency,and the nonsymmetric conformation of thiazloe could link many donors and acceptors and thus improves the β value.Experimental results show that the maximum absorption wavelength was 350~415 nm,the decomposition temperature was about 300℃,and the β value was 1×10^-30 esu,indicating a good nonlinearity-transparency-thermally stable comprehensive optimization has been achieved.
- thiazole,
- second-order nonlinear optical,
- synthesis and properties,
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