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Citation: GUO Jian-Ping, HUANG Xue-Yuan, YIN Du-Lin. Gel Polymer Electrolytes Prepared by in situ Radical Polymerization of Vinyl Monomers in Lewis Acid Ionic Liquid[J]. Chinese Journal of Applied Chemistry, ;2008, 25(6): 685-688. shu

Gel Polymer Electrolytes Prepared by in situ Radical Polymerization of Vinyl Monomers in Lewis Acid Ionic Liquid

1.
College of Chemistry and Chemical Engineering, Hunan Normal University, Changsha 410081

Corresponding author: GUO Jian-Ping,
Received Date: 7 July 2007
Available Online: 17 October 2007
Fund Project: 湖南省科技计划资助项目(2006JT2009) (2006JT2009)

Gel polymer electrolytes comprising 1-butyl-3-methylimidazolium-chloride-ZnCl₂[BMM](Cl-ZnCl₂) Lewis acid room temperature ionic liquid in PMMA matrix were prepared by means of in situ radical polymerization of vinyl monomers.The polymer matrix was formed by free radical polymerization of methyl methacrylate (MMA) monomers.Structure and properities of the product were studied by FTIR,AC,TG,GPC.The interactions and structure changes of [BMM]Cl-ZnCl₂/PMMA were investigated by FTIR,which showed composites structure.When n([BMM]Cl-ZnCl₂):n(MMA) is 7:3,the gel polymer electrolyte showed the maximum ionic conductivity of about 0.36×10^-3 S/cm at room temperature.The gel polymer electrolytes had greater thermal stability than the traditional non-aqueous electrolyte systems including organic solvent.They exhibited high decomposition temperatures above 286℃.M_w/M_n ratios of the gel polymer electrolytes were decresed as [BMM]Cl-ZnCl₂ mol content increased,which showed narrower molecular mass distribution.Ionic conductivities of the gel polymer electrolytes were increased as [BMM]Cl-ZnCl₂ mol content increased.
- ionic liquid,
- PMMA,
- polymer electrolyte,
- ionic conductivity,
- in situ radical polymerization
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Gel Polymer Electrolytes Prepared by in situ Radical Polymerization of Vinyl Monomers in Lewis Acid Ionic Liquid

南开大学师唯/华北电力大学（保定）刘景维：二维配位聚合物中有序的亲锂冠醚位点用于无枝晶锂沉积

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通讯作者: 陈斌, bchen63@163.com