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Citation: GUO Hong-Xu, CHEN Chen, CHEN Ling, LIANG Min, LIU Jia-Ming, WENG Wen. Hydrothermal Synthesis,Structure and Fluorescent Properities of Tetranuclear Copper Complex[J]. Chinese Journal of Applied Chemistry, ;2008, 25(6): 661-664. shu

Hydrothermal Synthesis,Structure and Fluorescent Properities of Tetranuclear Copper Complex

1.
Department of Chemistry and Envriomental Science, Zhangzhou Normal University, Zhangzhou 363000

Corresponding author: GUO Hong-Xu,
Received Date: 11 June 2007
Available Online: 8 September 2007
Fund Project: 国家自然科学基金(20705031)资助项目 (20705031)福建省教育厅资助省属高校研究项目(2006F5067) (2006F5067)漳州师范学院学生科研立项课题(200776) (200776)

The title complex[Cu₄Cl₄(bipy)₂] was hydrothermally synthesized and its crystal structure was determined by X-ray diffraction.It belongs to triclinic system with space group P-1.The cell parameters are:a=0.743 7(2) nm,b=0.942 99(4) nm,c=0.950 88(4) nm,α=64.164(3)°,β=74.170(3)°,γ=88.757(3)°,V=0.573 77(16) nm³,Z=1,D_x=2.050 g/cm³,μ(MoK_α)=4.139 mm^-1,F(000)=348,R₁=0.055 9,wR₂=0.162 5.The title compound consists of molecular units constructed around a Cu₄ parallelogram with obvious Cu…Cu bonds.The solid at room temperature exhibits intense red photoluminescence at 539 and 649 nm.Quantum chemistry calculations of the compound were performed with Guassian 03 program at HF/6-31G level to study the electronic structure and bonding characteristics.
- tetranucleare copper complex,
- hydrothermal synthesis,
- crystal structure,
- fluorescence spectrum,
- electronic structure
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