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Citation: LIU Xiao, YANG Xin-Guo, MO Xiong. Synthesis,Spectral Properties and Liquid Crystalline Behavior of Novel 1,4,5,8-tetra-Alkoxycarbonyl Substituted Naphthalene[J]. Chinese Journal of Applied Chemistry, ;2008, 25(8): 971-973. shu

Synthesis,Spectral Properties and Liquid Crystalline Behavior of Novel 1,4,5,8-tetra-Alkoxycarbonyl Substituted Naphthalene

LIU Xiao ^a ,
YANG Xin-Guo ^a,, ,
MO Xiong ^b

1.
a College of Materials Science and Engineering, Hunan University, Changsha 410082;
2.
b School of Chemistry and Chemical Engineering, Hunan University, Changsha 410082

Corresponding author: YANG Xin-Guo,
Received Date: 17 August 2007
Available Online: 1 December 2007
Fund Project: 国家自然科学基金(50573019)资助项目 (50573019)

Two novel compounds, 1,4,5,8-tetra-(4-n-butoxy-carbonyl)-naphthalene and 1,4,5,8-tetra-(8-n-octoxy-carbonyl)-naphthalene, were prepared from 1,4,5,8-naphthalene tetracarboxylic acid(NTA) with tetraoctane-ammonium bromide as a phase transfer catalyst. Their UV-Vis and fluorescent spectra suggested that the two compounds formed excimer complex in CH₂Cl₂, respectively. Their liquid crystalline behavior was investigated by DSC and polarized optical microscopy and their thermotropic liquid crystalline behavior was observed.
- naphthalene tetracarboxylic acid,
- phase-transfer catalysis,
- thermotropic liquid crystalline,
- synthesis
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